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Allotropism
Many shapes
appearance of one or more type of crystal types
Important in heat treatment, metal working, and welding
Anisotropy
a physical property that has a different value when measured in different direction
ex wood is strong along grain than across
basal plane
largest flat surface within a layered crystalline material
Body centered cubic (BCC) def and characteristics
atoms at each of its 8 corners and one atom in the center
48 possible slip systems
required high shear stress for slip, but many slip areas to happen
good strength, moderate ductility
can have higher ductility at higher temps
face centered cubic (FCC) def and characteristics
atoms located at the eight corners of the cube and at each center of the six faces
12 slip system, so chance of slip moderate
shear stress required for slip is low
moderate strength, good ductility
hexagonal close packed (HCP) def and characteristics
hexagonal prism with three layers, 6 corner atoms on top and bottom bases and 3 atoms int he middle of the prism, and 2 center atoms on the faces. 6 atoms per unit cell.
3 slip systems, low probability of a slip
slip more active at higher temps
brittle at room temps
cold working
plastic deformation carried out at room temp
covalent bond
sharing of electrons to achieve stable configuration
creep
gradual time dependent deformation of material under constant load or stress, accelerated by elevated temps
dislocation
a linear defect in a crystalline solid responsible for plastic deformation
elastic deformation
returns to OG shape after force is removed
embrittlement
process where a material, including metal, loses ductility and toughness, becoming brittle and more prone to cracking
grain
individual crystal within a polycrystalline structure like a metal
grain boundary
in polycrystalline materials is the boundary surface between adjacent crystals (grains)
grain growth
if temperature of the metal is raised the grains begin the grow and exceed the OG grain size
larger grains lead to rougher surface
adversely affect mechanical properties
grain size influence
smaller grain size increases a material’s strength and hardness as it creates more grain boundaries, impeding dislocation movement
larger grain size increases ductility by allowing for easier dislocation movement, can improve high temp creep resistance
homologous temp
T/Tm ratio where T is working temp and Tm is melting point
dimensionless
hot shortness
metal becoming brittle and prone to cracking when heated to high temp
hot working
when deformation occurs above the recrystallization temp
imperfections
point defects
linear defects
planar defects
volume defects
strengthening mechanisms
ionic bond
bond from oppositely charges ions formed when once atom completely transfers one or more electrons to another
mechanical fibering
type of anisotropy resulting from inclusions, impurities, and voids during deformation
impurities will weaken grain boundaries, so piece of metal will be weaker
metallic bond
force that holds metal atoms together in a solid formed by positive charges metal ions
nucleation
the initial stage of crystal formation
orange peel
rough surface appearance on sheet metals produced by larger grains
plastic deformation
permanent deformation - does not return to its original shape when the force is removed
polygonization
formation of subgrain boundaries
recovery
stressed in highly deformed regions of metal piece are relieved, subgrain boundaries begin to form with no significant change in mechanical properties
recrystallization
the “reset button” after being bent or stretched — when heated to the right temperature, it forms new, smooth, strain-free grains that replace the old, deformed ones, making the metal softer and more ductile again
shear stress
force acting parallel to area of material, causing planes within material to slide past each other
slip system
combination of a slip plane and its direction of a slip
slip plane
the adjacent plane of which a plane of atoms slips over under shear stress
work hardening/strain hardening
When more shear stress is needed to overcome obstacles in the metal’s structure, its overall strength and hardness increase
twinning
A deformation process where part of a crystal forms a mirror image of the rest, helping the metal change shape under stress (HCP structures)
vacancy
atom missing from a normally occupied position
interstitial
atom present in a position that is normally unoccupied
van der waals force
A weak attraction between molecules caused by temporary or uneven distribution of electric charges
Bauschinger Effect
When a metal is stretched and then compressed, it becomes easier to deform in the opposite direction — this is called strain softening or work softening
brittle fracture
no plastic deformation before fracture
compression
A force that pushes or squeezes a material, making it shorter or more compact
creep
time dependent deformation under load
deformation rate
speed at which a tension test is being carried out
disk test
A test where a disk is squeezed between two flat plates until it splits in half, showing how the material breaks under tension
ductile fracture
relatively large amounts of plastic deformation before fracture
elongation
measure of ductility of a material
ductility
ability of a material to stretch or deform before fracture
engineering strain
The amount a material stretches compared to its original length
egnineering stress
applied load divided by the original cross-sectional area of a material σeng=F/A0
true stress
applied load divided by the actual (instantaneous) cross-sectional area as the material deforms σtrue=F/Ainstantaneous
true strain
natural (logarithmic) strain considering continuous deformation εtrue=ln(L/L0)
fatigue
failure at relatively low stress levels
hardness
resistance to indentation
modulus of rupture
stress at fracture in bending
poisson’s ratio
relationship between axial and transverse strain
residual stresses
stresses that reaimin within a part after it has been formed and all the external forces are removed
strain rate
how quickly a material stretches, shorter specimens stretch faster than longer ones under same conditions
strain rate sensitivity exponenet
slope of temp and strain rate curves
superplasticity
ability of a material to undergo large uniform elongation before necking and fracture
tension
a force that pulls or stretches material
toughness
measure of the ability of a material to absorb energy up to fracture
ultimate tensile strength
max stress a material can withstand while being stretched before deformation
yield stress
stress at which a material starts to permanently deform
thermal conductivity
indicates the rate at which heat flows within and through a material as temp changes
metals have higher thermal conductivity
ceramics and plastics poor conductivity
materials with high electric conductivity typically have high thermal conductivity
thermal expansion
expansion or contraction of a material with change in temp
thermal stresses
thermal expansion creates stress, can also be caused by anisotropy of thermal expansion (uneven expansion)
thermal fatigue
caused by thermal cycling (heating, cooling, heating…) can cause surface cracks to form
conductors
materials with high electrical conductivity such as metals
super conductors
phenomenon of near-zero electrical resistivity that occurs in some metals and alloys below a critical temperature
application is high power magnets
semiconductors
extremely sensitive to temperature and impurities so by controlling these properties we can control electrical conductivity
used in microelectronics
electrical conductivity
material’s ability to conduct electrical current
dielectric strength
largest electric field an electrically insulating material can encounter without degrading or losing its insulating properties
ferromagnetism
high permeability and permanent magnetization that are due to the alignment of iron, nickel, and cobalt atoms into domains
used in electric motors, electric generators, etc
piezoelectric effect
Some materials change shape when electricity is applied, and produce electricity when pressed
Magnetostriction
expansion or contraction of a material when it is subjected to a magnetic field
galvanic corrosion
One metal corrodes faster when touching a different metal in water or electrolyte
stress corrosion cracking
Cracks form in metal under tension and a corrosive environment.
general corrosion
Metal corrodes evenly over its surface, like rust.
localized corrosion (pitting)
Small spots corrode faster than the rest of the metal.
caustic agent corrosion
Metal is damaged by strong chemicals like acids or bases.
pure metals
all atoms are the same type, except very small % of impurity atoms
99% pure minimum
alloys
a composition of two or more chemical elements, at least
one of which is a metal
interstitial solid solution
impurities are located in the spaces between the solvent atoms (interstices)
substitutional solid solution
impurities are located in sites normally occupied by solvent atoms
inter metallic compounds
structures consisting of two metals in which solute atoms are present among solvent atoms in certain proportions
typically strong, hard, and brittle
phase diagram
A diagram that shows which phases exist in an alloy at different temperatures and compositions when the system is stable
tie line
A horizontal line drawn at a specific temperature across a two-phase region on a phase diagram. It intersects the phase boundaries to show the compositions of the coexisting phases
ferrous
iron based
steel
iron alloyed primary with carbon but can be with Cr, Mo, Ni, etc
raw materials
iron ore, limestone, coke
blast furnace
A large furnace used to smelt iron from its ore by heating it with a combination of coke, limestone, and air, producing molten iron and slag
electric arc furnaces
A furnace that melts steel using a continuous electric arc between electrodes and the metal, typically from steel scrap, in a few hours
basic oxygen furnace
A steelmaking furnace where pure oxygen is blown into molten iron and scrap to remove impurities, producing steel and slag quickly and efficiently
fastest and far most common in the world
carbon steels
steels with carbon
low less than 0.3%
medium 0.3-0.6%
high higher than 0.6%
complex phase steels
very fine grain microstructures of ferrite and high volume of martensite and bainite
UTS strengths of 800 MPa
continuous casting
A process where molten metal is poured into a mold and solidified while being continuously pulled through rollers to form long, uniform shapes
continuous casting
A process where molten metal is poured into a mold and solidified while being continuously pulled through rollers to form long, uniform shapes
dual phase steels
mixed ferrite and martensite strcutre
high work hardening exponent
improved ductility and formability
High Strength Low Alloy Steels (HSLA)
steels with low carbon content less than 0.3%
fine grain ferrite as one phase and a hard second phase of martensite and austenite
ignot
solid form of molten steel
martensitic steels
Stainless steels that are hardenable by heat, magnetic, very strong and hard, with good fatigue resistance and moderate corrosion resistance