Carbocycles, Heterocycles, and Functional Groups Review

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Comprehensive vocabulary flashcards covering carbocycles, heterocycles, substituent placement rules, and organic functional groups from the combined lecture notes.

Last updated 9:36 AM on 9/8/26
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47 Terms

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Carbocycle

A ring structure made up only of carbon atoms.

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Ortho position

Substituent placement at positions 1,2 on a benzene ring.

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Meta position

Substituent placement at positions 1,3 on a benzene ring.

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Para position

Substituent placement at positions 1,4 on a benzene ring.

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Phenol

A carbocycle with the IUPAC name hydroxybenzene.

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Catechol

A carbocycle also known as pyrocatechol or o-dihydroxybenzene.

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Resorcinol

A carbocycle with the IUPAC name m-dihydroxybenzene.

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Hydroquinone

A carbocycle with the IUPAC name p-dihydroxybenzene.

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Xylene

A carbocycle with the IUPAC name dimethylbenzene, occurring in o-, m-, or p- isomers.

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Cresol

A carbocycle with the IUPAC names hydroxytoluene or methylphenol, occurring in o-, m-, or p- isomers.

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Benzoic acid

A carbocycle with the IUPAC name carboxybenzene.

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Salicylic acid

A carbocycle with the IUPAC name 2-hydroxybenzoic acid.

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Anthranilic acid

A carbocycle with the IUPAC names o-aminobenzoic acid or 2-aminobenzoic acid.

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Aniline

A carbocycle with the IUPAC name aminobenzene.

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Toluene

A carbocycle with the IUPAC name methylbenzene.

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Benzaldehyde

An aromatic carbocycle commonly known as bitter almond oil.

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Naphthalene

A bicyclic carbocycle commonly known as mothballs.

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Anthracene

A tricyclic carbocycle also known as paranaphthalene.

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Phenanthrene

A tricyclic carbocycle characterized as an ortho-fused benzenoid.

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Azido group

A functional group represented by the structure HN=N-NH\text{HN=N-NH}.

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Azo group

A functional group represented by the structure NH=NH\text{NH=NH}.

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Hydrazo group

The reduced form of an azo group, represented by the structure H-N-N-H\text{H-N-N-H}.

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Sulfonamide group

A functional group represented by the formula -SO2NH2\text{-SO}_2\text{NH}_2.

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Sulfoxide group

A functional group represented by the formula -SO\text{-SO}-.

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Sulfonyl group

A functional group represented by the formula -SO2\text{-SO}_2-.

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Acetyl group

A functional group represented by the structural formula H3C-C(=O)-\text{H}_3\text{C-C(=O)-}.

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Nitroso group

A functional group represented by the formula -NO\text{-NO}.

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Nitro group

A functional group represented by the formula -NO2\text{-NO}_2.

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Urea

A functional group or compound represented by the formula CO(NH2)2\text{CO(NH}_2)_2.

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Carbamate

A functional group listed under Part 2 of the new functional groups in the notes.

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Guanidine

A functional group listed under Part 2 of the new functional groups in the notes.

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Pyrrole

A 5-membered heterocyclic compound belonging to the "-ole" group containing one nitrogen atom.

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Imidazole

A 5-membered heterocyclic compound formed by adding a nitrogen atom to pyrrole (pyrrole + N).

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Oxazole

A 5-membered heterocyclic compound containing oxygen and nitrogen in its ring.

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Thiazole

A 5-membered heterocyclic compound containing sulfur and nitrogen in its ring.

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Indole

A bicyclic heterocycle composed of benzene fused with pyrrole.

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Thiophene

A 5-membered sulfur-containing heterocycle listed in Group II.

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Furan

A 5-membered oxygen-containing heterocycle listed in Group II.

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Puran

A 6-membered oxygen-containing heterocycle listed alongside thiophene and furan in Group II.

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Pyridine

A 6-membered nitrogen-containing aromatic heterocycle belonging to the "Py-" group.

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Pyrazine

A 6-membered aromatic heterocycle in the "Py-" group containing two para-positioned nitrogen atoms.

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Pyrimidine

A 6-membered aromatic heterocycle in the "Py-" group formed by adding a nitrogen atom to pyridine.

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Piperidine

A saturated 6-membered heterocycle containing one nitrogen atom, belonging to the "Pipe-" group.

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Piperazine

A saturated 6-membered heterocycle containing two opposite nitrogen atoms, belonging to the "Pipe-" group.

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Purine

A bicyclic heterocycle composed of a pyrimidine ring fused to an imidazole ring.

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Quinoline

A fused bicyclic heterocycle consisting of benzene fused to a pyridine ring.

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Isoquinoline

A fused bicyclic heterocycle that is a structural isomer of quinoline.