109C Coenzymes and Vitamins

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10 Terms

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Niacin (Vitamin B3)

-NAD+/ NADP+= oxidation (from alcohol to ketone)
- NADH/NADPH= reduction (alcohol to ketone)

<p>-NAD+/ NADP+= oxidation (from alcohol to ketone)<br>- NADH/NADPH= reduction (alcohol to ketone)</p><p></p>
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Riboflavin (Vitamin B2)

-FAD+= oxidation
- FADH2= reduction

<p>-FAD+= oxidation<br>- FADH2= reduction </p>
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Thiamine (Vitamin B1)

TPP
- acyl group transfer

<p>TPP<br>- acyl group transfer</p>
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Biotin (Vitamin B7)

Biotin
- carboxylation

<p>Biotin<br>- carboxylation</p>
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<p>Pyridoxine (Vitamin B6)</p>

Pyridoxine (Vitamin B6)

PLP
- decarboxylation
- racemization
- transamination

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Folic Acid

THF (N10-formyl-THF, N5-methyl-THF, N5,N10-methylene-THF)
one carbon transfer

<p>THF (N10-formyl-THF, N5-methyl-THF, N5,N10-methylene-THF)<br>one carbon transfer</p>
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Vitamin B5

Coenzyme A (CoASH)

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Vitamin B12

coenzyme 12
- isomerization (swaps H and another Y group from adjacent carbon)

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TPP-ylide

take out H bond from top to react

<p>take out H bond from top to react </p>
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Biotin forms

carboxybiotin and enolate

<p>carboxybiotin and enolate</p>