Redox Reactions
An oxidation and reduction reaction occurring together. Eg. cellular respiration
Oxidation Reaction
Movement of an electron to a lower energy state. Releases energy (exergonic) and typically coupled with a reduction reaction. Either gaining O, losing H (e-).
Reduction Reaction
Movement of an electron to a higher energy state - reduced molecules have higher potential energy than oxidized molecules. Stores energy (endergonic). Either losing O, gaining H (e-).
Electron Carrier
Molecule that moves electrons by moving H atoms. Eg. NAD+, FAD2+
Cellular Respiration
Conversion of glucose and oxygen into CO2m H2O and ATP. Composed of 4 steps
Glycolysis
Pyruvate Oxidation
Krebs Cycle
Electron Transport Chain
Anerobic Respiration
Respiration that is able to occur without O2. Eg. glycolysis
Aerobic Respiration
Respiration that needs O2, occurs in the mitochondria.
Eg. Pyruvate oxidation, krebs cycle, electron transport chain
Mitochondria
Double-membrane organelle where cellular respiration occurs.
Cristae
Intermembrane Space
Matrix
Cristae
Folds on the inner membrane to increase surface area to volume ratio
Intermembrane Space
Fluid-filled space between the two membranes of a mitochondria. Important for setting up the proton gradient for the ETC. Location of pyruvate oxidation, electron transport chain
Matrix
Innermost fluid-filled space. Location of krebs cycle
Glycolysis
Breaking down glucose into “simpler” sugars. Performed by all organisms but very inefficient - starting point of all cellular respiration. Anerobic. Occurs in the cytosol/cytoplasm. 1st half = phosphorylation, 2nd half = energy payoff.
C6H12O6 → 2 pyruvate + 2 ATP + 2NADH
Phosphorylation
Adding phosphates onto molecules to make them unstable. Used for exothermic reactions because the molecules become easy to split. 1st half of glycolysis → used to destabilize glucose by investing energy
Energy Payoff (Glycolysis pt2)
Production of NADH and ATP. Energy harvesting from glycolysis.
Substrate Level Phosphorylation
Metabolic reaction that produces ATP
Recycling NADH/NAD+
In bacteria: pyruvate converted to ethanol and CO2 (NADH → NAD+)
In animals: pyruvate converted to lactic acid (NADH → NAD+)
Lactic acid can be converted back to pyruvate to be oxidized in cellular respiration
Pyruvate Oxidation
Pyruvate + NAD+ → CO2 + acetyl-CoA + NADH
occurs twice per glucose
Aerobic process
NAD+ reduced, pyruvate oxidized
Krebs Cycle
Citric Acid Cycle. Occurs in mitochondrial matrix, catabolism of 6C citrate molecule.
Acetyl-CoA → 2 CO2 + 4 NADH + ATP + FADH2
Occurs twice for every glucose
Reduction of energy carriers
Energy carriers go to ETC
In total produces 4 CO2, 8 NADH, 2 ATP, 4 FADH2
Electron Transport Chain - Cellular Respiration
Chain of proteins in the inner mitochondrial membrane. Transports e- down ETC by creating H+ gradient to yield ~36 ATP. Only happens with O2 (aerobic respiration). Final e- acceptor in cell respiration is O2 (production of water)
ATP Synthase
Enzyme to set up H+ gradient to turn ADP and Pi → ATP
Chemiosmosis
Movement of H+ across a semipermeable membrane down their electrochemical gradient to produce ATP
Photosynthesis
Process by which plants produce glucose and oxygen from light energy, CO2, and H2O
CO2 + H2O + light → C6H12O6 + 6O2
Light dependent reaction
Light independent reaction
Light dependent Reaction
Occurs in the thylakoids where solar energy is converted to chemical energy.
Photosystem 2
ETC
Photosystem 1
Photosystem II
Photosystem where e- (excited by light energy) move to “primary e- acceptor” → e- constantly being lost, to replenish, photolysis occurs. Funnels e- into ETC (important for creating concentration gradient)
Electron Transport Chain - Photosynthesis
Movement of e- from PS1 to PS2. Creation of a proton gradient in inner membrane space of chloroplasts. Funnels e- into PS1
Photosystem 1
e- from ETC powers PS1 - “recharging e- after ETC”. Transfers e- into energy carriers (NADPH). Cyclic - e- either get used for NADPH or back to ETC for ATP synthase
Light Independent
Calvin Cycle. Occurs in the stroma, needs the products of the light reaction to drive synthesis (ATP and NADPH).
Attaching CO2 on to RuBP (5C) to make a 6C with rubisco enzyme
Carbon fixation
Occurs 6 times to make 2 G3P (1 glucose)
Uses energy from carriers to power cycle