Second Law of Thermodynamics

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58 Terms

1
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What happens with the internal energy when a system is returned to its initial state

There is no change

2
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What is a heat engine

A device that converts heat into work

3
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Over the whole cycle what does a heat engine do with heat energy

Absorb and reject

4
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How does a Carnot cycle operate

Reversibly between two temperatures

5
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Draw the Carnot cycle diagram

x

6
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Draw the Carnot cycle graph

x

7
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<p>What happens from A to B</p>

What happens from A to B

The gas expands isothermally at T1 and absorbs heat Q2

8
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<p>What happens from B to C</p>

What happens from B to C

The gas cools adiabatically from T1 to T2

9
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<p>What happens from C to D</p>

What happens from C to D

The gas contracts isothermally and T2 and rejects heat Q2

10
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<p>What happens from D to A</p>

What happens from D to A

The gas heat adiabatically from t2 to t1

11
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What processes does a Carnot cycle have

Two reversible isothermal and two revisable adiabatic

12
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What can the Carnot cycle be reversed to make happen

Extract heat from Q2 at T2 and reject heat Q1 at T1

13
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What is a heat pump/refrigerator

A device that uses work to continuously transfer heat from a hotter reservoir

14
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What is the working substance in a refrigerator called

Refrigerant

15
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What is need to extract heat from a colder reservoir to a hotter reservoir

Work

16
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What coefficient of performance does a Carnot cycle yield

Ideal

17
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What is Kelvin Statement

It is not possible to construct a thermodynamic system whose net effort is the complete conversion of heat into work

18
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What is Clausius statement

No thermodynamic system is process is possible whose net effect is the transfer of heat from a colder body to a hotter body

19
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What can the 2nd Law be defined by

Kelvin or Clausius statement

20
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What is Carnot’s Theorem

No heat engine operating between two thermal reservoirs can be more efficient that a Carnot engine operating between the same reservoirs

21
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What model is used for real engines

Air Standard

22
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What is the working fluid of an air standard engine and what is it taken as

Air taken as an ideal gas

23
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What is the Otto cycle

Simplified real petrol engine

24
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What is the Otto Cycle made up of

Two adiabatic processes linked with two isochoric processes combined with a fluid injection and exhaust stoke

25
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Draw an Otto Cycle

x

<p>x</p>
26
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<p>What Cycle is this </p>

What Cycle is this

Otto

27
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<p>What is happening from E to A</p>

What is happening from E to A

Air is drawn into the piston chamber isobarically

28
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<p>What does A to E model </p>

What does A to E model

Fuel intake stroke of a real petrol engine

29
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<p>What does A to B show </p>

What does A to B show

Air is compressed adiabatically and heats from T1 to T2

30
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<p>What is A does B model </p>

What is A does B model

Fuel compression stroke

31
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<p>What does B to C show</p>

What does B to C show

The pressure of the air increases isochorically due to heat entering the system

32
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<p>What does B to C model</p>

What does B to C model

Fuel ignition stage

33
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<p>What does C to D show </p>

What does C to D show

The air expanding adiabatically and cools

34
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<p>What does C to D model </p>

What does C to D model

Power stroke

35
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<p>What does D to A show </p>

What does D to A show

The pressure of the air decreasing isochorically

36
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<p>What does D to A model</p>

What does D to A model

Valve exhaust

37
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<p>What is A to E</p>

What is A to E

Air expelled from the piston chamber isobarically

38
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<p>What does A to E model</p>

What does A to E model

Exhaust stroke

39
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What is the diesel cycle made up of

Two reversible adiabatics an isobar and isochore

40
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What is this cycle

Diesel

<p>Diesel </p>
41
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Draw a diesel cycle

x

<p>x</p>
42
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<p>What does A to B show</p>

What does A to B show

The air is compressed adiabatically and heats

43
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<p>What is A to B modeled as </p>

What is A to B modeled as

Compression stoke

44
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<p>What does B to C show</p>

What does B to C show

The volume increases isobarically due to heat entering the system

45
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<p>What is B to C modeled as </p>

What is B to C modeled as

Fuel ignition

46
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<p>What does C to D show </p>

What does C to D show

Air expanding adiabatically and cooling

47
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<p>What is C to D modeled as</p>

What is C to D modeled as

Power stoke

48
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<p>What does D to A show </p>

What does D to A show

Pressure decreasing isochorically due to heat leaving

49
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<p>What does D to A model </p>

What does D to A model

Valve exhaust

50
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What do Stirling engines use as heat

Two thermal reservoirs

51
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<p>What is this graph </p>

What is this graph

Stirling

52
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Draw a Stirling Graph

x

<p>x</p>
53
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<p>What are the cycles in a Stirling cycle</p>

What are the cycles in a Stirling cycle

Two isotherms and two isochores

54
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<p>What happens from A to B</p>

What happens from A to B

The air contracts isothermally and rejects Q2

55
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<p>What happens from B to C</p>

What happens from B to C

Air absorbs the regenerator heat and the temperature increases isochorically

56
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<p>What happens from C to D</p>

What happens from C to D

The air expands isothermally and absorbs Q1 from the surroundings

57
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<p>What happens from D to A</p>

What happens from D to A

The air deposits the regenerator heat and its temperature decreases

58
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<p>What is an ideal Stirling cycle </p>

What is an ideal Stirling cycle

A carnot