Structure

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10 Terms

1

Describe the structure of diamond

  • Giant covalent structure

  • Each carbon forms 4 sigma bonds to 4 others

  • Giant 3D tetrahedral arrangement

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2

Explain the electrical conductivity and strength of diamond

  • Does not conduct as there are no free electrons or ions

  • Hard as carbon forms 4 bonds, rigid structure preventing any movement

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3

Describe the structure of graphite

  • Each carbon forms 3 sigma bonds to 3 others

  • The 4th electron in the p orbital, close enough to overlap so delocalised electrons are above and below layers

  • Weak forces between layers

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4

Explain the electrical conductivity and strength of graphite

  • High conductivity as there are delocalised electrons between layers which are free to move - only conduct to parallel layers

  • Soft due to weak london forces between layers which are easily broken so layers can slide

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5

What is graphene

One layer of graphite

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6

Describe the strength of graphene

Strong but can be fractured

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7

Describe the structure (bonds) of silicon dioxide

  • Each silicon forms 4 bonds with oxygen atoms

  • Each oxygen forms 3 bonds with silicon atoms

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8

Explain the electrical conductivity and strength of silicon dioxide

  • does not conduct electricity as there are no free electrons or ions

  • Hard as forms a rigid structure

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9

Describe the structure of C60 fullerene

  • Each carbon forms 3 bonds

  • The 4th electron is delocalised over surface

  • Balls can slide over each other as only weak forces between balls

  • Simple molecular structure

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10

Explain the boiling point and electrical conductivity of C60 fullerene

  • Low BP due to weak intermolecular forces between molecules

  • Low conductivity as electrons cannot move between balls

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