Alkene Addition Reactions

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33 Terms

1

HBr

Hydrohalogenation

<p>Hydrohalogenation</p>

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2

H2SO4, H2O

Acid Catalyzed Hydration (or Hydration)

<p>Acid Catalyzed Hydration (or Hydration)</p>

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3

Cl2 or Br2

Halogenation

<p>Halogenation</p>

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4

X2, H20

Halohydrin Formation

<p>Halohydrin Formation</p>

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5

1) Hg(OAc)2, H2O
2) NaBH4

Oxymercuration-Reduction

<p>Oxymercuration-Reduction</p>

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6

1. BH3, THF 2. H2O2, NaOH

Hydroboration-Oxidation

<p>Hydroboration-Oxidation</p>

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7

OsO4

Dihydroxylation

<p>Dihydroxylation</p>

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8

(1) O3; (2) S(CH3)2

Ozonolysis

<p>Ozonolysis </p>

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9

addition of hydrogen and metal catalyst
(H2, Pd)

Hydrogenation

<p>Hydrogenation</p>

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10

NaOCH3

E2

<p>E2 </p>

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11

H2O

SN1

<p>SN1</p>

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12

NaNH2

alkyne deprotonation

<p>alkyne deprotonation</p>

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13

H2O, HgSO4, H2SO4

oxymercuration of alkynes

<p>oxymercuration of alkynes</p>

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14

NaCN

SN2

<p>SN2</p>

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15

Cl2 MeOH

Halohydrin Formation

<p>Halohydrin Formation</p>

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16

<p>draw acid-catalyzes dehydration reaction</p>

draw acid-catalyzes dehydration reaction

check

<p>check</p>

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17

H2, Lindlar (cat.)

alkyne to alkene

<p>alkyne to alkene</p>

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18

t-BuOK

E2, side group to alkene

<p>E2, side group to alkene</p>

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19

TsCl (or MsCl), pyridine (or Et 3N)

conversion of OH to OTs or OMs

<p>conversion of OH to OTs or OMs</p>

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20

PBr3

SN2

<p>SN2</p>

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21

PCC

oxidation of alcohols

<p>oxidation of alcohols</p>

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22

H2CrO4

oxidation of alcohols (creates carboxylic acid)

<p>oxidation of alcohols (creates carboxylic acid)</p>

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23

NaNH2 (on side group, no alkyne)

removes hydrogen

<p>removes hydrogen</p>

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24

X 2 (Br2 or Cl2), heat or light

halogenation of alkanes

<p>halogenation of alkanes</p>

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25

mCPBA

epoxidation of alkene

<p>epoxidation of alkene</p>

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26

HBr, Peroxides

hydrohalogenation; anti-markovnikov

<p>hydrohalogenation; anti-markovnikov</p>

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27

<p>draw halohydrin formation reaction</p>

draw halohydrin formation reaction

check

<p>check</p>

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28

HCN

Cyanohydrin Formation

<p>Cyanohydrin Formation</p>

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29

NBS, light

allylic bromination

<p>allylic bromination</p>

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30

CH3OH, H2SO4

epoxi to OCH3

<p>epoxi to OCH3</p>

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31

give the structure of the product of oxidative cleavage of cis-1,2-cyclopentanediol with HIO4. Draw both the starting material and the product

check

<p>check</p>

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32

NaOH

strong base, E2

<p>strong base, E2</p>

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33

give the structure of the product of oxidative cleavage of cis-1,2-cyclopentanediol with HIO3. Draw both the starting material and the product

check

<p>check</p>

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