Entropy and the 2nd and 3rd laws of thermodynamics

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Flashcards related to key vocabulary terms regarding entropy and the laws of thermodynamics.

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5 Terms

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Boltzmann’s constant (k)

R/NA = 1.38 × 10–23 J∙K–1

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Multiplicity (W)

The number of microstates that are compatible with a system’s macrostate.

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Macrostate

The observable state of the system as defined by its state functions (T, P, etc.).

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Microstate

An instantaneous “snapshot” of a system showing the position and momentum of each atom.

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Standard Molar Entropy (Sm˚)

The absolute molar entropy at 298.15 K and 1 bar pressure.