Cell Bio Exam 2: pt. 1 - Bioenergetics

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79 Terms

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bioenergetics

the flow of energy in the cell

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what is energy

the capacity to cause specific chemical or physical changes

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what 6 categories of change require energy

synthetic, mechanical, concentration, electrical, generation of heat, and generation of light

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what is synthetic work

changes in chemical bonds

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what is an example of synthetic work

the process of photosynthesis

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what does biosynthesis do

aids in growth and maintenance of cells and cellular structures

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what is mechanical work

changes in the location or orientation of a cell or subcellular structure

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what is often required for movement

cilia or flagella

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what is an example of mechanical work in the body

muscle contraction

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what is concentration work

moving molecules across a membrane against a concentration gradient

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what does concentration work do

accumulates substances within a cell or removes toxic by-products

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what are examples of concentration work in a cell?

the concentration of specific molecules and enzymes in organelles and import of sugar/amino acids into cells

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what is electrical work

moving ions across a membrane against an electrochemical gradient

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what happens during electrical work

ions are transported across a membrane

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what is the result of ions being transported across a membrane

a difference in concentration and electrical potential

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what is an example of electrical work in cells

the membrane potential of mitochondrion

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what is heat work

an increase in temperature that is useful to warm0blooded animals

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what is a homeotherm

animals that regulate their body temperature independent of the environment

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What is bioluminescence?

the product of light by living organisms (fireflies)

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how is bioluminescence generated?

by the reaction of ATP with luminescent compounds

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what is a type of fluorescent protein useful to biologists?

green fluorescent protein

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how do organisms obtain energy

phototrophs: sunlight

chemotrophs: oxidation of chemical compounds

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how do phototrophs get energy from sunlight?

they use solar energy to produce all the carbon compounds they need from CO2

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how do chemotrophs get energy from oxidation of chemical compounds?

they oxidize chemical bonds in organic molecules (carbohydrates)

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what is the equation for phototroph's synthesis of light?

CO2 + H2O -> sugars +O2

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what is the equation for chemotroph's synthesis of sugars?

sugars + O2 -> CO2 +H2O

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What 4 atoms cycle continuously between phototrophs and chemotrophs?

carbon, nitrogen, oxygen, and phosphorous

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what is oxidation

the removal of electrons from a substance, usually hydrogen atoms and addition of oxygen atoms

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do oxidation reactions release energy

yes

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what is reduction

the addition of electrons to a substance through addition of hydrogen atoms (and loss of oxygen atoms)

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do reduction reactions require energy

yes

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what is energy flow in the universe governed by

3 laws of thermodynamics

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what is thermodynamics

area of science that deals with energy transactions that accompany all physical and chemical processes

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what is the "system" in thermodynamics

the energy under consideration in any particular case

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what is the "surroundings" in thermodynamics

everything outside the system

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what is a closed system

it is sealed from the environment and can neither take nor release energy

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what is an open system

it can have energy added to it or removed from it

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are organisms open or closed systems

open

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what does the exchange of energy between a system and its surroundings occur as?

heat or work

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why is heat not a useful energy source for cells?

because many biological systems are isothermal (at a fixed temperature)

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what is work?

the use of energy to drive a process other than heat flow

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what is the unit for quantifying energy changes during chemical reactions?

calorie/kcal

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what unit of energy do physicists prefer?

joules (J)

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How many calories is one Joule?

0.239 calories

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what is the first law of thermodynamics?

law of conservation of energy: energy cannot be made or destroyed

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what is the total energy stored within a system called?

internal energy

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what is delta E?

the difference in internal energy of a system before a process (E1) and after it (E2)

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How is delta E written in a chemical reaction?

delta E = E products - E reactants

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what do biological processes focus on calculating in a system?

enthalpy

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what is enthalpy (H)?

the heat content of a system

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does delta E usually equal delta H?

yes because there is little change in pressure and volume in biological reactions

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how is enthalpy change calculated for a reaction?

delta H = delta H of products - delta H of reactants

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What does it mean if delta H is negative?

it is an exothermic reaction; energy is released

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what is an example of an exothermic reaction?

burning gasoline in a car

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what does it mean if delta H is positive?

the reaction is endothermic, energy is absorbed

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what is an example of an endothermic reaction?

melting of an ice cube

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what is the second law of thermodynamics?

reactions have directionality; they can proceed spontaneously only in one direction

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what is thermodynamic spontaneity?

a measure of whether or not a reaction or process can occur

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what does it mean for a reaction to be thermodynamically spontaneous?

it is a favorable reaction

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what is entropy (S)

measure of randomness of disorder

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when does entropy increase in a system?

when the system becomes disordered

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when does entropy decrease in a system

when the system becomes more ordered

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what is free energy (G)

the measure of spontaneity for a given system; gibbs free energy

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what is every spontaneous reaction characterized by

a decrease in free energy of the system

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how do you calculate delta G?

delta G = G products - G reactants

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what does it mean if delta G < 0

the reaction is thermodynamically spontaneous

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how do you calculate delta G in a system?

delta H - T*delta S

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when does delta G increase

when delta H increases

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when does delta G decrease

when delta S increases

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what is an exergonic reaction

an energy-yielding reaction that occurs spontaneously

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is the oxidation of glucose exergonic or endergonic

exergonic

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What is the delta G calculated for the oxidation of glucose?

-686 kcal/mole

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what is an endergonic reaction

energy is required and it does not occur spontaneously

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is the reduction of carbon dioxide endergonic or exergonic?

endergonic

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what is the delta G calculated for the reduction of carbon dioxide?

+686 kcal/mole

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what is the rate of a reaction at equilibrium?

the forward and backward rates are the same

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what would happen if a cell reached equilibrium?

it would be dead

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what makes life possible?

cells maintaining a steady state and never reaching equilibrium

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what makes it possible for cells to remain in a steady state?

the cell being an open system that receives energy from the environment