Chapter 4 Chem

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Duality

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46 Terms

1

Duality

when waves can exhibit particle-like properties while particles can exhibit wave-like properties

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2

Electromagnetic Radiation

a form of energy that exhibits wave-like behavior as it travels through space

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3

What is the number for the speed of light?

3.0x10⁸ m/sec

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4

Wavelength(λ)

the distance between two consecutive peaks or troughs in a wave

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5

Frequency(v)

the number of waves pass a given point in a specific amount of time (usually a second)

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6

What is the equation for the energy of light?

E=h(v)

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7

What is the equation for the speed of light?

C=λ(v)

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8

What is the electromagnetic spectrum?

1.radio waves 2.microwaves 3.infrared waves 4. visible light 5. ultraviolet 6. x-rays 7.gamma rays

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9

Photon

quantum (particle) of light

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10

Quantum

a finite quantity of energy that can be gained or lost by an atom

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11

What is the photoelectric effect?

when a photon falls on the surface of a metal, the entire photon's energy is transferred to the electron.

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12

Max Planck

proposed that an object that is hot loses energy in specific amounts or quanta

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13

Photoelectric effect

when a photon falls on the surface of a metal, the entire photon's energy is transferred to the electron

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14

Ground state

lowest energy of an atom and stable electrons

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15

Excited state

a higher potential energy than the ground state

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16

What is Planck's constant (a.k.a. H)?

6.626x10^-34Js

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17

What does the Heisenberg Uncertainty Principle state?

it is impossible to determine simultaneously booth the position and velocity of an electron or any other particle

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18

How are electrons detected?

their interaction with photons

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19

________ and _______ have about the same energy.

Electrons; photons

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20

The Scrodinfer wave equation laid the ___________ for modern quantum theory. It applies to ___ _______.

foundation; all atoms

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21

How did Erwin Schrodinger help modern quantum theory?

he treated the electron as a wave and developed an equation to describe its wave like behavior

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22

Quantum Numbers

The address of an electron

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23

Principle quantum number

(n) how far from the nucleus the electron is

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24

Angular quantum number

(l) the shape of the orbital

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25

What shape does s stand for and what does it look like?

Sharp; sphere

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26

What shape does p stand for and what does it look like?

Principal; infinity sign

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27

What shape does d stand for and what does it look like?

Diffuse; 4 leaf clover

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28

What shape does f stand for and what does it look like?

Fundamental; fireworks

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29

How do you find the angular quantum number?

n-1 and then whatever that is between 0

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30

Magnetic quantum number

(m) Indicated the position of the orbital about the three axes in space (orientation)

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31

What is the orientation of the sharp orbital?

1 orientation

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32

What is the orientation of the principle orbital?

3 orientation

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33

What is the orientation of the diffuse orbital?

5 orientation

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34

What is the orientation of the fundamental orbital?

7 orientation

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35

Spin Quantum Number

(s) a clockwise and counterclockwise electron can fit into each sub-level +½ or -½

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36

Aufbau Principle

an electron occupies the lowest energy level that can receive it

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37

Orbital Diagram

[][][][]

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38

Longhand electron configuration

1s2s2p3s

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39

Hund’s Rule

Orbitals of equal energy are each occupied by one electron before any is occupied by a second electron and all electrons in singly occupied orbitals must have the same spin

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40

Equal charges _______ each other

repel

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41

No two electrons in the same atom can have the same __________ ____________

quantum numbers

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42

Octet Rule

Only 8 electrons may occupy the outermost main energy level

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43

An atom is _____ _______ when there are 8 electrons in the outermost main energy level

most stable

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44

Valence electrons

electrons on the outside at its highest energy level

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45

Core electrons

electrons on the inside at its lowest energy level

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46

What do valence electrons determine?

the properties of an atom and how it acts

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