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Chemistry
the science that describes matter—its properties, the changes it undergoes, and the energy changes that accompany those processes
Chemistry
The CENTRAL SCIENCE
Organic chemistry
(Branch of Chemistry) Hydrocarbons and its derivatives
Inorganic chemistry
(Branch of Chemistry) Inorganic compounds, metals, minerals
Analytical chemistry
(Branch of Chemistry) Detection and identification of substances present (qualitative analysis) or amount of each substance (quantitative analysis)
Biochemistry
(Branch of Chemistry) processes in living organisms
physical chemistry
(Branch of Chemistry) behavior of matter
matter
anything that has mass and occupies space
mass
measure of the quantity of matter
volume
amount of space
energy
the capacity to do work or to transfer heat
kinetic energy
energy in motion
potential energy
energy at rest
exothermic
release of heat
endothermic
absorbs heat
solids
molecules packed close together orderly
gas
highly compressible state of matter
liquid
molecules are close but randomly arranged
melting
solid to liquid
freezing
liquid to solid
gas
expands indefinitely
boiling
liquid to gas
condensation
gas to liquid
deposition
gas to liquid
sublimation
solid to gas
dry ice
tx of skin diseases (eczema, psoriasis)
physical properties
can be observed or measured without changing the identity of the substance
chemical properties
exhibited by matter as it undergoes changes in changes in composition
physical
(physical or chemical property) color
chemical
(physical or chemical property) iron reacts with oxygen to form rust
chemical
(physical or chemical property) hydrogen has the potential to ignite and explode given the right conditions
physical
(physical or chemical property) hardness
physical
(physical or chemical property) melting point
physical
(physical or chemical property) boiling point
extensive properties
dependent on the amount of substance
intensive properties
independent on the amount of substance
intensive
(extensive or intensive property) density
extensive
(extensive or intensive property) mass
extensive
(extensive or intensive property) volume
intensive
(extensive or intensive property) electrical conductivity
intensive properties
(extensive or intensive property) specific gravity
intensive
(extensive or intensive property) boiling/melting point
extensive
(extensive or intensive property) size
chemical change
(physical or chemical change) one or more substance are used up
physical
(physical or chemical change) no change in chemical composition
physical change
(physical or chemical change) reversible
chemical change
(physical or chemical change) irreversible
chemical change
(physical or chemical change) one or more new substances are formed
physical change
(physical or chemical change) boiling of water
chemical
(physical or chemical change) energy is absorbed or released
chemical change
(physical or chemical change) burning of paper
chemical change
(physical or chemical change)souring of milk
chemical change
(physical or chemical change) cooking an egg
chemical change
(physical or chemical change) fireworks exploding
chemical change
(physical or chemical change) formation of solid when two solutions are mixed
mixture
(classification of matter) variable composition (e.g. 80% ethanol in water)
pure susbtance
(classification of matter) fixed composition
pure substance
(classification of matter) cannot be separated into simpler substances by physical methods
mixture
(classification of matter) may be separated into pure substances by physical methods (e.g. distillation, filtration)
homogeneous mixtures
(classification of matter) components are not distinguishable
heterogeneous mixtures
(classification of matter) multiple phases
homegenous mixture
(classification of matter) single phase
homogenous mixtures
(classification of matter) have same composition throughout
heterogeneous mixtures
(classification of matter) components are distinguishable
heterogenous mixtures
(classification of matter) do not have same composition throughout
compounds
(classification of matter) can be decomposed to simpler substances by physical by chemical changes
elements
(classification of matter) cannot be decomposed to simpler substances by chemical change
elements
(classification of matter) consists of only one kind of atom
compounds
(classification of matter) consists of atoms of two or more different elements bound together
oxygen, silicon, aluminum
top 3 most abundant elements in the earth’s crust, ocean
atom
the smallest unit that retains the properties of an element
Dalton’s Theory
(theory) all matter is composed of atoms and these cannot be made or destroyed
atomos
meaning “uncuttable”
positive
charge of nucleus
PROTONS
determines atoms’ identity
number of protons
this number is known as the atomic number of that element
mass number of atom
is the sum of the number of protons amd the number of neutrons in its nucleus
𝑴𝒂𝒔𝒔 𝑵𝒖𝒎𝒃𝒆𝒓 = 𝑨𝒕𝒐𝒎𝒊𝒄 𝑵𝒖𝒎𝒃𝒆𝒓 + 𝑵𝒆𝒖𝒕𝒓𝒐𝒏 𝑵𝒖𝒎𝒃𝒆𝒓
mass number =
isotopes
are atoms of the same elements with different masses
isotopes
they are atoms containing the same number of protons but different numbers of neutrons
isobars
different element, same mass
isotones
different elements, same number or neutrons
Nuclide Symbol
represents the composition of the nucleus
𝑵𝒐. 𝒐𝒇 𝑵𝒆𝒖𝒕𝒓𝒐𝒏𝒔 = 𝑴𝒂𝒔𝒔 𝑵𝒖𝒎𝒃𝒆𝒓 − 𝑨𝒕𝒐𝒎𝒊𝒄 𝑵𝒖𝒎𝒃𝒆𝒓
# of Neutrons =
fractional numbers
Atomic weights are __ numbers, not integers.
Leucippus and Democritus
they described atom as solid indivisible sphere
aristotle and others
said matter is made up of four elements
John Dalton
described atom as solid sphere but NOT indivisible
John Dalton
who discovered Solid Sphere (Billiard Ball) Model
Humphry Davy
“elements of a chemical compound are held together by electrical forces”
Michael Faraday
“Relationship between the amount of electricity used in electrolysis and the amount of chemical reaction that occurs.”
” “Electrons” → Electric ions“
George Stoney
Cathode-Ray Tube Experiment
most convincing evidence of electrons
Joseph John Thomson
conducted Cathode-Ray Tube Experiment
Robert Milikan
conducted Oil-drop experiment
Joseph John Thomson
discovered electrons
Cathode-Ray Tube Experiment (J.J. Thomson)
Plum pudding model experiment
Oil-drop Experiment (Robert Milikan)
determine the charge of electrons
Hantaro Nagaoka
created Saturn-like model
Eugen Goldstein
he conducted Canal Rays Experiment