ORGANIC CHEMISTRY EXAM 1 REVIEW

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29 Terms

1
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H-Cl

-7

2
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CH3CO2-H

4.8 (4.76)

3
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NH4+ (ammonium)

9.27

4
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HO-H

15.7 (14)

5
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CH3CH2O-H

16

6
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HC≡CH (≡—H)

25

7
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H-H

35

8
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H2N-H

Ammonia - Wikipedia

38

9
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CH2=CH2

44

10
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H3C-H

50

11
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number of pi electrons formula

2 x (# of pi bonds + # of delocalized lone pairs)

12
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Degree of Unsaturation formula (DoU)

2C + 2 - H + N - X / 2

13
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What are the 3 rules to find significant resonance?

  1. Greatest filled octet

  2. Least amount of formal charges

  3. A structure w a negative charge on the more EN element is more important

14
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Alkene

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15
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Alkyne

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16
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Aromatic compound/ring

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17
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Alkyl Halide

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18
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Alcohol

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19
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Ether

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20
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Amine

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21
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thiol

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22
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Sulfide

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23
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Aldehyde

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24
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Ketone

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25
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Carboxylic Acid

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26
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Ester

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27
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amide

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28
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Acid Chloride

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29
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2 rules to determine which compound is more acidic?

  1. E.N for same row

  2. SIZE for same column