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What were the four classical elements proposed by Empedocles?
Earth, air, fire, and water
What was Aristotle's fifth element?
Ether
What is an element?
A substance that cannot be broken down into simpler substances by ordinary chemical means
What is the Law of Conservation of Mass?
The total mass of the reactants equals the total mass of the products; mass is not created or destroyed
What is the Law of Definite Proportions?
A specific compound always contains the same elements in the same fixed proportions
What is the Law of Multiple Proportions?
The same elements can combine in different ratios to form different compounds, such as CO and CO2
Which ancient element symbols should I recognize?
Fe, Pb, Hg, Ag, Sn
Who created an early periodic table in 1869?
Dmitri Mendeleev
How did Mendeleev arrange his periodic table?
By increasing atomic mass while grouping elements with similar properties
Why did Mendeleev leave gaps in his periodic table?
He predicted that undiscovered elements would eventually fill them and predicted their properties
How is the modern periodic table arranged?
By increasing atomic number
What is the Periodic Law / periodicity?
When elements are arranged by increasing atomic number, their properties repeat in predictable patterns
What is a period?
A horizontal row on the periodic table
What is a group or family?
A vertical column; elements in the same group have similar properties
Where are metals, nonmetals, and metalloids located?
Metals are mainly left/centre, nonmetals are mainly right, and metalloids are along the staircase
What are Groups 1, 2, 17, and 18 called?
Group 1 Alkali Metals; Group 2 Alkaline Earth Metals; Group 17 Halogens; Group 18 Noble Gases
What groups are the transition elements?
Groups 3-12; they are all metals
What is the general main-group combining-capacity pattern?
+1, +2, +3, +4, -3, -2, -1, 0
What is unusual about hydrogen's position?
Hydrogen can show properties similar to both Group 1 and Group 17
What diatomic elements should I memorize?
HOBrFINCl = H2, O2, Br2, F2, I2, N2, Cl2
What multiatomic elemental forms should I remember?
Phosphorus is P4 and sulfur is S8
What is atomic radius and what is its trend?
Atomic radius is atom size; it decreases moving right and increases moving down
What is ionization energy and what is its trend?
Energy required to remove the outermost electron; it increases moving right and decreases moving down
What equation represents ionization energy?
M + energy → M+ + e-
What does M represent in an ionization-energy equation?
A generic neutral atom
What is electronegativity and what is its trend?
How strongly an atom attracts bonding electrons; it increases moving right and decreases moving down
What is electron shielding?
Inner electrons reduce the nucleus's attraction for the outer electrons
How does gaining or losing electrons affect ion size?
Gaining electrons makes a negative ion larger; losing electrons makes a positive ion smaller
Why is F- larger than F?
The extra electron increases electron-electron repulsion, making the electron cloud larger
How do you find valence electrons from a simple electron configuration?
Look at the last number; for example, 2-8-7 has 7 valence electrons
How do valence electrons identify main-group groups?
1→Group 1, 2→Group 2, 3→Group 13, 4→14, 5→15, 6→16, 7→17, 8→18
What do metals and nonmetals generally do when forming ions?
Metals lose electrons and form positive ions; nonmetals gain electrons and form negative ions
What are the key Group 1 and Group 2 facts?
Group 1 forms +1 ions and gets more reactive down; Group 2 forms +2 ions, is less reactive than Group 1, and gets more reactive down
What are the key Group 17 and Group 18 facts?
Group 17 forms -1 ions and gets less reactive down; Group 18 has full outer shells and is very unreactive
What should I know about transition metals, lanthanides, and actinides?
Transition metals can have multiple charges and form coloured compounds; lanthanides are 57-71 and usually +3; actinides are 89-103 and radioactive
What is the trend for metallic character
How strongly an element shows metal properties; increases going LEFT and DOWN on the periodic table.