Chapter 10 - Alcohols

Phenol

OH group on benzene ring

When naming, the — has priority.

OH group

Alcohols have a pH of

weakly acidic

Phenol + OH forms

Phenoxide Ion

R + O + Na forms

Alkoxide Ion

Synthesis of glycols (occurs via?)

Syn Hydroxylation (OsO4+H2O2, cold KMnO4) and Anti Hydroxylation (peroxyacids, hydrolysis)

Organometallic reagents are made of —-. The —- attaches the ——.

Carbon and metal; carbon; partially positive carbon.

Grignard Reagent Is formed with

R-Mg-X + Ether

Organolithium reagent is formed with

R-Li + any hallide

Grignard + formaldehyde forms

Primary alcohol

Grignard + Ethylene Oxide forms

Primary alcohol with 2 additional carbons

Grignard + aldehyde forms

Secondary alcohol

Grignard + Ketone forms

Tertiary alcohol

Grignard + Acid Chlorides/Esters form

Tertiary alcohols with identical alkyl groups