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Kinetic Molecular Theory (KM)
gas molecules move in random straight-line motion
gas molecules undergo elastic collisions with their container walls and other particles
Differentiate between diffusion
flow of a gas through a small orifice and effusion - mixing of gases in a system of gases
Four characteristic that are needed to completely define a gas
pressure, number of moles, volume, temperature
pressure
force per unit area, # of collisions per defined area
volume
usually defined as the volume of its containerte
temperature
always use kelvin
torrs
mmHg
STP Standard Temperature and Pressure conditions
0 degrees celcius, 273.15K, 1 ATM
standard molar volume
1 mole of any gas at STP occupies 22.4L
Boyle’s Law
when the temperature and number of moles of a gas are held constant, the pressure of the gas varies indirectly with its volume
Charle’s Law
when the pressure and number of moles of a gas are held constant, the volume of the gas vaires directly with its temperature
Gay-Lussac’s Law
when the volume and number of moles of a gas are held constant, the pressure vaires directly with its temperature
Avagardro’s Law
when pressure and temperature of a gas are held constant the volume of a gas varies directly with the number of moels of the gas (opposite of Gay- Lussac’s Law)
In each of the four laws, there are always
two variable which change and two which remain constant
Combined Gas Law
Use this formula when you have one of the four characterisitcs changing. If one of the four is not mentioned, assume STP and ignore the variable.
Dalton’s Law
the sum of the partial pressures of the gases in a system equals the total presure to solve partial pruesure gas law problems. the total pressure is usually read directly from the barometer