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activation energy
the minimum amount of energy required by reacting particles in order to form the activated complex and lead to a reaction
alloy
a mixture of elements that has metallic properties
atom
the smallest particle of an element that retains all the properties of that element; is electrically neutral, spherically shaped, and composed of protons, neutrons, and electrons
aufbau principle
states that each electron occupies the lowest energy orbital available
Avogadro's number
the number 6.02 x 10^23 which is representative of the number of particles in a mole
average atomic mass
determined by multiplying each number isotope by the percent, and adding all of the products
anion
an ion that has a negative charge; forms when valence electrons are added to the outer energy level
atomic number
the number of protons in an atom
cation
an ion that has a positive charge; forms when valence electrons are removed, giving the in a stable electron configuration
chemical property
the ability or inability of a substance to comine with or change into one or more new substances
catalyst
a substance that increases the rate of a chemical reaction by lowering the activation energy
coeffecient
the number written in front of a reactant or product
combined gas law
a single law combing boyles, charles, and lussacs laws that states the relationship among pressure, volume, and temp of a fixed amount of gas
combustion reaction
a chemical reaction that occurs when a substance reacts with oxygen, releasing energy in the form of heat and light; hydrocarbon + oxygen yields carbon dioxide + water
covalent bond
a chemical bond that results from the sharing of valence electrons; electronegativity difference is less than 1.7; two or more nonmetals
cathode ray
J.J. Thompson's experiment in which he discovered electrons and protons; created the plum pudding model
compound
combination of two or more elements
Dalton's atomic theory
5 part theory; right
Dalton's law of partial pressures
states that the total pressure of amixture of gases is equal to the sum of the pressures of all the gases in the mixtures
decomposition reaction
a chemical reaction that occurs when a single compound breaks down into two or more elemtns or new compounds
delocalized electrons
the electrons involved in metallic bonding that are free to move easily from one atom to the next throughout the metal and are not attached to any particular atom
deposition
when substance changes from gas/vapor to a solid, without first becoming liquid
double replacement reaction
a chemical reaction that involves the exchange of positive ions between two compounds and produces either a precipitate, a gas, or water
dipole
dipole forces
electron
a negatively charged, fast moving particle found in the empty space surrounding nucleus
electron configuration
the arrangement of electrons in an atom
electronegativity
indicates the relative ability of an elements atoms to attract electrons in a chemical bond
element
a pure substance that cannot be broken down into simpler subtances by physical or chemical means
endothermic
a chemical reaction in which a grater amount of energy is required to break the existing bonds than is released when the new bonds form in the product molecules; heat absorbed
exothermic
a chemical reaction in which more energy is released than is required to break bonds in the initial reaction; heat released
heterogenous mixture
one that does not have a uniform composition and in which the individual substances remain distinct
homogeneous mixture
one that has a uniform composition throughout and always has a single pahse; also called a solution
hydrogen bond
a strong dipole dipole attraction bw molecules that contain a hydrogen atom bonded to a small, highly electronegative atom with at least one lone electron pair; usually N, O, F
ideal gas law
PV=nRT; temp in kelvin, R depends on P units
isotopes
atoms of the same element with the same number of protons, but different number of neutrons
ionic bond
metal with a nonmetal; hard, rigid, brittle solids, high melting and boiling points, conducts electricity in the aqueous and molten states
insoluable
describes a substance that cannot be dissolved in a given solvent
ionization energy
the energy required to remove an electrn from a gaseous atom; generally increases left to right, and decreases tope to bottom. (florine=greatest)
joule
the SI unit of heat and enegy
kinetic molecular theory
explains the properties of gases in terms of the energy, size, and motion of thier particles
law of conservation of energy
states that in any chemical or physical process, energy may change from one form to another, but it is neither created, nor destroyed
law of conservation of mass
in any physical change or chemical reaction, mass is conserved; mass can be neither created nor destroyed
Lewis Dot structure
a model that uses electron dot structures to show how electrons are arranged in molecules; lines represent bonding pairs
limiting reactant
reactant that is totally consumed during a chemical reaction, limits the exten of the reaction and dtermines the amount of product
matter
anything that has mass and takes up space
mixture
a physical blend of two or more pure substances in any proportion in which each
molecule
forms when two or more atoms covalently bond and is lower in potential energy than its constituent atoms
mass number
the number after the elements name, representing the sum of its protons and neutrons
metal
left side of periodic table; good conductor of heat and electricity, ductile, malleable, generall shiny
metalloid
an element that has properties of both metals and nonmetals; found along the steps lines on periodic table
metallic bond
the attraction of a metallic cation for delocalized electrons
molecular formula
a formula that specifies the actual number of atoms of each element in one molecule or formula unit of the substance; done after empirical formula
empirical formula
percent to mass, mass to mole, divide by small, multiply till whole
heat of fusion
the amount of heat required to melt one mole of a solid substance; 334j/g; Q=mHf
heat of vaporization
the amount of heat required to evaporate one mole of a liquid; 2260j/g; Q=mHv
molarity
the number of moles of solute dissolved per liter of solution; moles of solute/liters of solution
molar mass
the mass in grams of one mole of any pure substance
molar volume
for a gas, the volume that one mole occupies; 22.4 at one mole
mole
the SI base unit used to measure the amount of a substance
neutron
a neutral subatomic particle in an atoms nucleus that has a mass nearly equal to that of a proton
group
the vertical column of elements in the periodic table
noble gas configuration
electron configuration in which you incorporate the noble gas to replace a group of configurations
neutralization reaction
a reaction in which an acid and base react in aqueous solution to produce a salt and water
nonmetal
elements on the right side of periodic table; generally dull gases, brittle solids, and poor conductors of heat and electricity
octet rule
states that atoms lose, gain, or share electrons in order to acquire a full set of eight valence electrons
Pauli exclusion principle
states that a maximum of two electrons may occupy a single atomic orbital, but only if the electrons have opposite spins
pH
the negative logarithm of the hydrogen ion concentration of a solution; 1
period
a horizontal row of elements in the periodic table
physical change
a type of change that alters the physical properties of a substance but does not change its composition
physical property
A characteristic of a matter that can be observed without changing the samples composition; ex. density, color, taste, etc
photon
a particle of electromagnetic radiation with no mass that carries a quantum of energy
polar covalent
a type of bond that forms when electrons are not shared equally
precipitate
a solid produced during a chemical reactin in a solution
product
a substance formed during a chemical reaction
proton
a subatomic particle in an atoms nucleus with a positive charge a 1+
reactant
the starting substance in a chemical reaction
excess reactant
a reactant that remains after a chemical reactant starts
saturated
contains the maximum amount of dissolved solute for a give amount of solvent at a specific temp and pressure
single replacement reaction
a chemical reaction that occurs when the atoms of one element replace the atoms of another element in a compound
solute
a substance dissolved in a solution
soluble
describes a substance that can be dissolved in a give solvent
solvent
the substance that dissolves a solute to form a solution
solution
a uniform mixture that may contain solids, liquids, or gases
sublimation
solid changes to directly to a gas w/o becoming liquid first
supersaturated
contains more dissolved solute than a saturated solution at the same temperatrue
synthesis reaction
a chemical reaction in which two or more substances react to yield a single product
temperature
a measure of the average kinetic energy of the particles in a sample of matter
unsaturated solution
contains less dissolved solute for a given temp and pressure than a saturated solution
valence electrons
the electrons in an atoms outermost orbitals; determines the elements chem properties
heat
a form of energy that flows from a warmer object to a cooler object
Q=mCpT
specific heat formula