mistaken reactions

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47 Terms

1
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Methyl benzene to benzoic acid

hot, alkaline, KMnO4, reflux, (dilute)

2
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alcohol to haloalkane

kcl, conc h2so4 or H3po4

3
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carboxylic acid to acyl chloride

pcl3, heat or pcl5

4
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SO2 reaction w NaOH

Na2SO3 + H2O

5
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ketone to hyrdroxynitrile

HCN, KCN heat

6
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PCl5 + H2O

H3PO4, HCl

7
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P4O10 + H2O

H3PO4

8
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Phenylamine to phenol

heat, water (N2 gas) (black oily product)

9
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Phenylamine to diazonium ion

HNO2, Ice, 5, HCl

10
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Formation of nitrous acid (unstable)

NaNO2, HCl, Ice

11
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Formation of Azo dye (diazonium ion is electrophile)

Diazonium ion, Phenol, NaOH (deprotonate)

12
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Benzene to cyclohexane

H2, Pt (or Ni heat)

13
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Phenol to trinitrophenol

Conc HNO3

14
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Benzene to Nitrobenzene

Conc, H2SO4, HNO3, reflux, 55

15
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Nitrile to amine

H2, Ni or LiAlH4, dry ether

16
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Amine to Amide

Acyl chloride, cold

17
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Amide to Amine

LiAlH4, dry ether

18
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compare amide hydrolysis with acid vs alkali

COOH, ammonium salt vs COO- ion, NH3

19
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Nitrile to carboxylic acid

dilute HCl, H2O, reflux

20
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Compare nitrile hydrolysis w acid vs alkali

COOH, ammonium salt vs COO- ion, NH3

21
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ester to COOH or OH (acid)

dilute H2SO4, reflux

22
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ester to COOH or OH (alkali)

NaOH, HCl, reflux

23
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relative acidities of carboxylic acids (1), phenols (2) and alcohols (3) (least to most)

321

24
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Relative acidities: ethanoic acid (1), chloroethanoic acid (2) least to most

12

25
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Phenylamine to tribromophenylamine

Br2, (room temp) (white ppt)

26
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Acyl chloride + NH3

Amide

27
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Acyl chloride + Amine

Amide

28
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COOH + SOCl2

Acyl chloride, SO2, H2O

29
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COOH + PCl5

Acyl chloride, POCl3, HCl

30
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Methanoic acid to CO2, H2O

Hot, conc, acidified, KMnO4

31
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Acyl Chloride to COOH

H2O

32
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COOH + PCl3

heat, acyl chloride, H3PO3

33
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Alcohol to Alkene (w/o catalyst)

conc, H2SO4, 180, reflux

34
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Alcohol to Alkene (w catalyst)

Hot, Al2O3

35
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Alcohol to chloroalkane

KCl, conc H2SO4

36
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by product organic + PCl3

H3PO3

37
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by product organic + PCl5

POCl3

38
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by product organic + SOCl2

SO2

39
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Haloalkane to nitrile

KCN, reflux, alcoholic

40
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Haloalkane to amine

XS NH3 (or amine), Pressure, Alcoholic,

41
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Alkene to Alkane

H2, Ni, 150

42
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Alkene to Alcohol

Steam, H3PO4, 60 atm, 300

43
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thermal cracking conditions

1200k, 7000Kpa

44
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catalytic cracking condtions

zeolite, 720k

45
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nitrobenzene to phenylamine

Sn, conc, hcl, reflux

46
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amide + reducing agent

amine

47
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diazonium ion to phenol

heat (>10) h2o