3.3 Second Law of Thermodynamics and Entropy

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What is Entropy S ?

  • J/K

  • a measure of disorder or randomness in a system and thus the uncertainty or unpredictability pf data.

  • quantifies the number of ways microscopic components can be arranged.

  • Higher entropy means more disorder.

<ul><li><p><span style="color: oklch(0.872 0.01 258.338)">J/K</span></p></li><li><p><span style="color: oklch(0.872 0.01 258.338)">a measure of disorder or randomness in a system and thus the uncertainty or unpredictability pf data.</span></p></li><li><p><span style="color: oklch(0.872 0.01 258.338)">quantifies the number of ways microscopic components can be arranged. </span></p></li><li><p><span style="color: oklch(0.872 0.01 258.338)">Higher entropy means more disorder.</span></p></li></ul><p></p>
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What becomes the entropy equation if the process is isothermal ?

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What is the second law of thermodynamics ?

if a process is applied : Consider a certain amount of gas enclosed in a cylinder–piston chamber and an external compressive force is applied on the piston to decrease the chamber’s volume

In a closed system, the entropy of the system increases for irreversible processes

It remains constant for reversible processes and never decreases

<p><strong>if a process is applied : Consi</strong><span>der </span><strong>a</strong><span> </span><strong>certa</strong><span>in </span><strong>amou</strong><span>nt </span><strong>o</strong><span>f </span><strong>g</strong><span>as </span><strong>enclo</strong><span>sed </span><strong>i</strong><span>n </span><strong>a</strong><span> </span><strong>cylin</strong><span>der–</span><strong>pist</strong><span>on </span><strong>chamb</strong><span>er </span><strong>a</strong><span>nd </span><strong>a</strong><span>n </span><strong>exter</strong><span>nal </span><strong>compres</strong><span>sive </span><strong>for</strong>ce is <strong>appli</strong>ed <strong>o</strong>n <strong>t</strong>he <strong>pist</strong>on <strong>t</strong>o <strong>decre</strong>ase <strong>t</strong>he <strong>chamb</strong>er’<strong>s</strong> <strong>volu</strong>me</p><p><strong>I</strong>n <strong>a</strong> <strong>clos</strong>ed <strong>syst</strong>em, <strong>t</strong>he <strong>entro</strong>py <strong>o</strong>f <strong>t</strong>he <strong>syst</strong>em <strong>increa</strong>ses <strong>f</strong>or <strong>irrevers</strong>ible <strong>proces</strong>ses </p><p><strong>It remai</strong>ns <strong>const</strong>ant <strong>f</strong>or <strong>reversi</strong>ble <strong>proces</strong>ses and <strong>nev</strong>er <strong>decrea</strong>ses</p>
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What is the cycle of carnot ?

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