Alkyl Halide Reactions

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Last updated 6:33 AM on 8/4/26
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30 Terms

1
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Primary

Strong Base

Poor Nucleophile

E2

2
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Secondary

Strong Base

Poor Nucleophile

E2

3
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Tertiary

Strong Base

Poor Nucleophile

E2

4
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Primary

Weak Base

Poor Nucleophile

no rxn

5
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Secondary

Weak Base

Poor Nucleophile

Sn1 + E1

6
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Tertiary

Weak Base

Poor Nucleophile

Sn1 + E1

7
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Primary

Weak Base

Good Nucleophile

SN2

8
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Secondary

Weak Base

Good Nucleophile

SN2

9
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Tertiary

Weak Base

Good Nucleophile

SN1 (RARE)

10
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Primary

Strong Base

Good Nucleophile

Sn2>E2

11
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Secondary

Strong Base

Good Nucleophile

E2>SN2

12
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Tertiary

Strong Base

Good Nucleophile

E2

13
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CH3X

Strong Base

Weak Nucleophile

no rxn

14
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CH3X

Strong Base

Strong Nucleophile

sn2

15
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CH3X

Weak Base

Strong Nucleophile

sn2

16
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CH3X

Weak Base

Weak Nucleophile

no rxn

17
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-OC(CH3)3 (text-butoxide), DBN, DBU, LDA

bulky bases

18
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-Oh, -OCH3, -OCH2CH3, NaOMe

small bases

19
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-OC(CH3)3 (tert-butoxide)

strong base, weak nucleotide

20
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DBN, DBU, LDA

Strong base, weak nucleophile

21
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-OH

strong base, strong nucleophile

22
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-OCH2CH3, NaOEt

strong base, strong nucleophile

23
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-OCH3, NaOMe

strong base, strong nucleophile

24
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-I, -Br, -Cl, -N3

weak base, strong nucleophile

25
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-CN

weak base, strong nucleophile

26
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-SH, -SR, -H2S, -RSH

weak base, strong nucleophile

27
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CH3CO2- (acetate)

weak base, strong nucleophile

28
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H2O

weak base, weak nucleophile

29
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CH3OH (methanol)

weak base, weak nucleophile

30
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CH3CH2OH (ethanol)

weak base, weak nucleophile