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How is haloalkanes made
We heat the ethanol (alcohol) under reflux, with a mixture of sodium bromide and sulfuric acid (50% conc)
We form bromoethane, water and sodium hydrogen sulfate
Whats first stage of halogenation
The sodium bromide and sulfuric acid react together, forming hydrogen bromide and sodium hydrogen sulfaete.

Whats second stage of halogenation of ethanol
The hydrogen bromide reacts with ethanol, to form bromoethane and water.

How is halogenation a substitution reaction
We substitute OH group of alcohol with bromine atom.

How do we separate haloalkane
They are volatile molecules, so distillation can be used.