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Longer distance leads to
weaker attraction
Strongest IMF
Ion-Dipole
2nd strongest IMF
H-bond
Least soluble ions
Ions with small radii and large charge magnitude
Like Disolves ___
Like
What elements accept H bond
N, O, and F
Unsaturated solution
Below solubility limit at given temp.
Miscible
2 liquids mix completely, forming homogenous solution
Immisicible
2 liquids do NOT intermix, forming heterozygous mixture
Hydrophobic
Generally nonpolar, lack of H-bonds, heavy (ex. oil)
Kelvin in 0 degrees C
273.15
Weak acids are also
Weak electrolytes
Lower temp=
less kinetic energy
Reaction rate formula
Factors that help increase reaction rate
High temp, high concentration (pressure), high surface area, Positive catalysts, chemical properties (smaller tends to be faster)
Higher van Hoff constant will do what to vapor pressure
Hydrocarbon Van Hoff constant always=
Van Hoff constant=1
How is instantaneous rate determined
taking slope of a line tangent to its curve
First order
1:1 proportional relationships between reactant and reaction rate
Catalyst that slows down a reaction rate
Negative Catalyst
Endothermic
Energy is absorbed (+)
Exothermic
Energy is lost (-)
Sum of all exponents on reactants (all exponents added up)
Order of reaction
Stonger IMF forces
higher boiling point
Activated complex
Top of “hill” on graph
Rate of reaction (for reactant
=(-)(1/coefficient)(change of reactant/change in time)