Chem 206 Test 3 Reactions & Reagents

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Last updated 8:34 PM on 4/28/26
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17 Terms

1
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<p>tautomerization (a)</p>

tautomerization (a)

H3O+

2
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<p>tautomerization (b)</p>

tautomerization (b)

KOH, H2O

3
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<p>aldol addition</p>

aldol addition

KOH/H2O, 0˚C

4
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<p>aldol condensation</p>

aldol condensation

KOH/H2O, heat

5
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<p>kinetic alkylation of ketones</p>

kinetic alkylation of ketones

1. LDA, -78 ˚C

2. R-X

6
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<p>thermodynamic alkylation of ketones</p>

thermodynamic alkylation of ketones

1. NaNH2, -78 ˚C or LDA, 40 ˚C

2. R-X

7
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<p>alkylation of aldehydes</p>

alkylation of aldehydes

1. 2˚ amine

2. R-X

3. H3O+

8
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<p>halogenation of aldehydes and ketones (a)</p>

halogenation of aldehydes and ketones (a)

Br2 (or Cl2), AcOH

9
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<p>halogenation of aldehydes and ketones (b)</p>

halogenation of aldehydes and ketones (b)

Br2 (or Cl2), KOH

10
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<p>conjugate addition (1-2 and 1-4)</p>

conjugate addition (1-2 and 1-4)

1. EtMgBr

2. H3O+

11
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<p>michael addition</p>

michael addition

1. LDA

2. H3O+

12
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<p>robinson annulation</p>

robinson annulation

NaOEt, heat or 1. KOH/H2O 2. H3O+

13
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<p>mannich reaction</p>

mannich reaction

1. amine, H+

2. KOH

14
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<p>claisen condensation</p>

claisen condensation

1. NaOR (OR matches ester)

2. H3O+

15
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<p>decarboxylation</p>

decarboxylation

1. NaOH

2. H3O+, heat

16
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<p>conjugate addition (1-2)</p>

conjugate addition (1-2)

1. EtLi

2. H3O+

17
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<p>conjugate addition (1-4)</p>

conjugate addition (1-4)

1. Et2CuLi

2. H3O+