CPL - MT 3&4

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47 Terms

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Soaps

are compounds with the general formula R-COO-M where 'M' is an alkali element, where the R-COO component is a fatty acid radical

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Detergents

are synthetic organic chemicals that are generally more effective at lowering surface tension than soaps

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Biologically Soft Syndets

detergent compounds that can be easily oxidized into simple, harmless end-products

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Batch Saponification

the oldest form of soap manufacturing, which offers two options: acid hydrolysis or direct saponification

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Continuous Hydrolysis or Saponification Process

a method of soap manufacturing that provides greater flexibility in controlling the product distribution of fatty acids and glycerin, and yields higher glyceride (over 80%)

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Caustic Soda and Vegetable Oils

specific raw materials used for toilet soap production

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Sodium Silicate

a common additive in soap production, functioning as an economical filler and an antioxidant particularly used in laundry soap bars

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Allyl Chloride Route

a method of glycerine production that involves a series of reactions starting with the chlorination of propylene to produce allyl chloride

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Acrolein Route

a method of glycerine production, which has a multi-step process starting with the oxidation of propylene to acrolein

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Micelles

detergent molecules aggregate into spherical clusters called

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Surfactants

are compounds that significantly affect, and typically reduce, the surface tension of water or the interfacial tension between two liquids

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Surfactant Molecule

a long chain with a hydrophilic (water-loving) end and an hydrophobic (water-hating or soil-loving) end

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Hydrophobic End (of a surfactant molecule)

attach to the dirt particles surrounding them

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Hydrophilic End (of a surfactant molecule)

pull the entire molecule-dirt complex away from the fabric and into the wash water

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Fatty Alcohols

are produced from a fatty acid through processes like that Ziegler Catalytic Procedure and the Methyl Ester Hydrogenation Process

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Ziegler Procedure

also known as the "alfol alcohols" process, manufactures C12 to C18 a-olefins and even-numbered straight-chain fatty alcohols ideal for detergents

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Methyl Ester Hydrogenation Process

a method to produce fatty alcohol where methyl esters of fatty acids are prepared by reacting refined oil with methanol, catalyzed by a small amount of sodium methylate

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Builders

are class of additives used in detergent to enhance their cleaning power

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Corrosion Inhibitors

an additive used to protect metal parts if washing machines, as well as utensils and dishes, from the corrosive effects of detergents and water

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Anti-redeposition Agents

an additive used to prevent soil that has been removed from re-settling onto fabrics

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Fabric Brighteners

are fluorescent dyes that absorb ultraviolet light and re-emit it as visible light

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Bluing Agents

an additive used to counteract the natural yellowing tendency of fabrics, improving their whiteness

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Antimicrobial Agents

an additive used to kill microbes and provide a sanitizing effect

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Anionic Detergents

is a type of detergent that gives a negative charge in water and are derived from compounds like sulphated fatty alcohols or sulphonated esters

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Cationic Detergents

is a type of detergent that give a positive charge in water and, while not strong cleaners, possess germicidal properties

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Non-ionic Detergents

a type of detergent that produce very little foam but are excellent at removing soil and emulsifying grease

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Amphoteric Detergents

a type of detergent also known as zwitterionic detergents, which have both positive and negative charges within a specific pH range, resulting in a net zero charge

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Sulphated Fatty Alcohols

are high molecular weight alcohols, like lauryl alcohol and oleyl alcohol, that are derived from natural sources, most notably from coconut oil

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Sodium Reduction

a method to obtain sulphated fatty alcohols that involves slowly adding molten sodium to the coconut oil

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Catalytic Hydrogenation

a method to obtain sulphated fatty alcohols that is performed at high temperatures (200-300°C) and pressures (100-200 atm) using copper salts as catalysts

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Alkyl-aryl Sulphonates

are a different class of detergents, manufactured from inexpensive petroleum raw materials like kerosene

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Fermentation

a natural process utilizing microbiology to produce chemical compounds

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Batch Processes

often preferred for longer processes of fermentation or where there is a high risk of contamination and microbial mutation

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Fermentation Processing

a method of production that relies on biological action, utilizing substrates like sucrose and starch to produce the desired compound

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Petroleum Processing

a method of production that utilizes chemical reactions derived from petroleum

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Hydrolysis of Sucrose

a process of producing ethyl alcohol from sugar where sucrose reacts with water in the presence of the enzyme invertase to from two molecules of glucose

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Fermentation of Glucose

a process of producing ethyl alcohol from sugar where the glucose is converted into ethanol and carbon dioxide by the enzyme zymase

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Fusel Oil

a mixture of higher alcohols and aldehydes, which is a product formed from the side reaction of ethyl alcohol production from sugar

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Slops

a liquid waste at the bottom of the beer still that can either be discharged as water, or concentrated by evaporation to produce cattle feed

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Ternary Azeotropic Distillation

a method to achieve 100% alcohol, which uses a third component, like benzene, to facilitate separation

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Citric Acid

a highly versatile organic acid used as an acidulant in food and beverages, as an ion-sequestering agent in medicine, and as a plasticizer

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Penicillin

the first antibiotic discovered, found by Alexander Fleming in 1929

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Antibiotics

are chemical substances produced by specific microorganisms that can inhibit the growth of or destroy harmful bacteria

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R-group derivatives

group of derivatives that determines the specific type of penicillin produced

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M-group derivatives

group of derivatives that controls how the penicillin is administered and its action speed

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Phenyl Acetic Acid

an organic precursor chemical used to control the type and yield of a Type II penicillin

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Penicillium Chrysogenum

a specific mold culture used for the inoculation of a Type II penicillin