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INTERNAL ENERGY CHANGE (ΔU)
Sum of heat added and work done on system; ΔU = q + w
FIRST LAW OF THERMODYNAMICS
Energy conserved; change in system internal energy = heat in + work done on system
POSITIVE q
Heat enters system
NEGATIVE q
Heat leaves system
POSITIVE w
Work done ON system by surroundings
NEGATIVE w
Work done BY system on surroundings
POSITIVE ΔU
Net energy gain; internal energy increases
NEGATIVE ΔU
Net energy loss; internal energy decreases
STATE FUNCTION
Property dependent only on initial/final states, not path; U, H, T, V are state functions