Ch 20: Redox Reactions

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Joel Karty

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REACTIONS FOR REDUCTION OF CARBONYL GROUPS TO METHYLENE GROUPS

Wolff Kishner, Clemmensen, Mozingo reductions

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How do aldehydes undergo catalytic hydrogenation?

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How do imines undergo catalytic hydrogenation?

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How do nitriles udergo catalytic hydrogenation?

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How do alkenes undergo catalytic hydrogenation

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How do alkynes undergo catalytic hydrogenation? (Pd, Pd/C, Pt, Ni catalyst)

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<p>How do alkynes undergo catalytic hydrogenation? (Pd, CaCO3, BaSO4, quinoline) </p>

How do alkynes undergo catalytic hydrogenation? (Pd, CaCO3, BaSO4, quinoline)

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What are the conditions for the wolf-kischner reduction?

basic conditions

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What are the conditions for the clemmensen reaction? 

acidic conditions 

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What reagents and conditions are used for Mozingo reduction?

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How do you oxidize a primary alcohol to a carboxylic acid?

Jones oxidation CrO3 with H2SO4

<p>Jones oxidation CrO3 with H2SO4</p>
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How do you oxidize a primary alcohol to an aldehyde?

PCC or NaOCl3