Mechanisms for Test 3 (Organic Chemistry)

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Last updated 7:58 PM on 7/6/26
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5 Terms

1
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Halogenation

Example: When cyclohexene reacts with chlorine in carbon tetrachloride the
trans-dichloride is formed.

<p><span>Example: When cyclohexene reacts with chlorine in carbon tetrachloride the</span><br><span>trans-dichloride is formed. </span></p>
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Hydrohalogenation

Example: When methylcyclohexene reacts with HCl, 1-chloro-1-methylcyclohexane
is formed

<p><span>Example: When methylcyclohexene reacts with HCl, 1-chloro-1-methylcyclohexane</span><br><span>is formed</span></p>
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Oxymercuration - Demercuration

Example: The reaction sequence below shows the hydration of an alkene
(including the regiochemistry) using mercuric acetate and water, followed by
sodium borohydride.

<p><span>Example: The reaction sequence below shows the hydration of an alkene</span><br><span>(including the regiochemistry) using mercuric acetate and water, followed by</span><br><span>sodium borohydride.</span></p>
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Hydrohalogenation with 1,2 -alkyl shift

Example: The reaction for the hydrobromination of 3,3 dimethylcyclopentane is shown below. While there are two possible products, only the major product — which is the result of a carbocation rearrangement (1,2 methyl shift)

<p>Example: The reaction for the hydrobromination of 3,3 dimethylcyclopentane is shown below. While there are two possible products, only the major product — which is the result of a carbocation rearrangement (1,2 methyl shift)</p>
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Halodydrin formation

Example: The reaction of bromine in water with methylcyclohexene. It should also be noted that another water molecule could also remove the proton in the third step.

<p><span>Example: The reaction of bromine in water with methylcyclohexene. It should also be noted that another water molecule could also remove the proton in the third step.</span></p>