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U
internal energy
ΔU
change in internal energy
q
heat
w
work
H
enthalpy
ΔH
enthalpy change
m
mass
c or s
specific heat capacity
C_cal
calorimeter heat capacity
ΔT
T_f - T_i
ΔH_f^°
standard enthalpy of formation
q > 0
the system absorbs heat
q < 0
the system releases heat
w > 0
work is done on the system
w < 0
work is done by the system
ΔH < 0
exothermic
ΔH > 0
endothermic
first law of thermodynamics
ΔU = q + w
heating or cooling equation
q = mcΔT
calorimeter equation
q_cal = C_calΔT
energy-conservation equation
q_rxn = -q_surroundings
formation-enthalpy equation
ΔH_rxn^° = ΣνΔH_f^°(products) - ΣνΔH_f^°(reactants)
Hess's law: reverse a reaction
reverse the sign of ΔH
Hess's law: multiply an equation
multiply ΔH by the same factor
Hess's law: add equations
add their ΔH values