Metal Hydride Reducing Agents
Studied by 0 people
Learn
Practice Test
Spaced Repetition
Match
Flashcards1/7
There's no tags or description
Looks like no tags are added yet.
Name | Mastery | Learn | Test | Matching | Spaced |
|---|
No study sessions yet.
8 Terms
What are the products of LiAlH4 strong reducing agent?
Everything undergoes substitutions and nucleophilic addition to form primary, secondary, and tertiary alcohol and amide
What are the reagents of NaBH4?
Aldehyde and ketone
What are the products of NaBH4 reducing aldehyde and ketone?
Primary and secondary alcohol
What is the reagent of LiAlH[OC(CH3)3]3?
Acid chloride
What is the product of LiAlH[OC(CH3)3]3 to acid chloride?
Aldehyde
What is the reagent of DIBAL-H?
Ester RCOOR’
What is the product of DIBAL-H reducing ester?
Aldehyde
Why are DIBAL-H and LiAlH[OC(CH3)3]3 weaker hydride reducing agent than LiAlH4?
Because they are bulkier, less reactive so they can only to substitution step
Stop at the nucleophilic addition