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Flow of energy begins with what
sun
kinect energy=
energy of motion
potential energy=
stored energy
1 calorie = (small calories not capital)
heat required to raise 1 gram of water by 1C
Calorie with capital C
represents 1 thousand lowercase calories
Leo the Lion says Gerrr
losing electrons means oxidation, gaining electrons means reduction
First law of Thermodynamics
energy cannot be created or destroyed meaning energy can only be created or destroyed, some energy is lost as heat duirng conversion
Second law of thermodynamics
Entropy (disorder) is continiously increasing, energry trasnformations are spontaneus
G=
H=
T=
S=
G =energy available to do work, enthalpy (energy in a molecules bonds), absolute temperature (C+273), S= entropy
equation for energy
G=H-TS
delta G equation
delta G = delta h - T delta S ofc delta always means change
positive delta G reactions means that
the product shave more free energy than reactants (higher H or lower s)
exergonic
spontaneous and releases energy
endergonic
non spontaneus and requires and input of energy
negative delta G
products have less energy than reactants
Active site
allows for percise fit of substate applies stress to lower activation energy
induced fit
enzymes change shape to maximize contact with substrate
factors that influence enzyme structure
temp, pH, inhibitors aka regulatory molecules, and concentration of substrate and enzyme
competitive inhibtor
compete with substrate for the active site
non competitive inhibotior
binds to enzyme at a site (allotsteric site) other than active site it causes a change in shape and unable to bind to substrate
allosteric enzymes means
can be inactive and active
metabolism
total of all chemical reactions carried out by an organism
anabolic reactions
spend energy to synthesize molecules
catabolic reactions
harvest energy by the breaking down stuff
feeback inhibitio
automatic shut off switch that keeps the cell from making too much
AtP stores energy
in the covalent bonds on the phosphate groups
ATP is constantly synthesized and used
atp hydrolysis is used by cells to drive endergonic reactions
coupled reactions
an exergonic reation is combined with an endergonic reactions net negative delta g
Autotrophs (algae, photosynthetic bacteria, etc)
Make their own ATP through photosynthesis can also extract energy from organic molecules
Heterotrophs 95% of species (animals, fungi, etc
cannot make its own food must live off other eating other organisms
cellular respiration involves enzyme catalyzed does
does oxidation and dehydrogenation
dehydrogenation
loss of protons
series of redox reactions
electrons posses energy and when transfered lose some energy with each transfer releasing energy to become ATP after sometime they have no more energy left
cofactors
small chemicals that assist enzymes
NAD+ electron carrier
accepts two electrons and one proton from a substrate molecule to form NADH
NAD+ is _____ to form NADH and to revert NADH to NAD+ what do you do
reduced and oxidiation
formula for cellular respiration
C6H12O6 + 6O2 to 6CO2 + 6H20 + energy
Oxygen is so important in Aerobic respiration because
it is the final electron acceptor
4 stages of cellular respiration and where it occurs
Glycolysis in cytosol, Pyruvate oxidation in mitochondrial matrix, Krebs cycle mitochondrial matrix, Electron transport chain and Chemiosmosis inner mitochondrial membrane called the cristae
where do prokaryotes perform cellular respiration
conduct all recations in cytoplasm or plasma membrane
First stage of Glycolysis
gluclose is converted into two G3P molecules and a hydorlysis of 2 ATP molecules
Second Phase of glycolysis
convers each G3P molecule into pyruvate
how many atp is produced from one gluclose and how many atp does glycolysis make
4 atp and 2 atp bc 2 atp is used in the start
ATP generated during glycolysis is called
substrate level phosphorylation
Pyruvate Oxidation
is carried out by the enzyme pyruvate dehydrogenase and this process releases releases two electrons to reduce NAD+ to NADH
each pyruvate molecule is used to generate
1 Co2, 1 NADH, 1 Acetyl CoA
what does the Krebs Cycle do
oxidizes the acetyl generated by pryuvate oxidation
3 main parts of the krebs cycle
Making Citrate, Carbon Loss & Energy Harvest, Regenerating Oxaloacetate
For each Acetyl CoA entering the Krebs cycle
release two molecules of CO2, reduce 3 NAD+ to NADH, reduce 1 FAD to FADH2, procude 1 ATP, regenerate oxaloacetate