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An element
a substance that cannot be broken down to other substances by chemical reactions
A compound
substance consisting of two or more elements in a fixed ratio
Carbon, hydrogen, oxygen, nitrogen
make up 96% of living matter
Remaining 4% of living matter
Calcium, Phosphorous, Potassium, Sulfur
Atom
The smallest unit of matter that still retains the properties of an element
Neutrons and protons
form the atomic nucleus and measured in daltons
Atomic number
number of protons in a nucleus, can be approximated by the mass number
Mass number
Sum of protons plus neutrons in the nucleus
All atoms of an element
Have the same number of protons but may differ in number of neutrons
Isotopes
two atoms of an element that differ in number of neutrons
Parent isotope
decays into daughter isotope (half-life)
Potential energy
The energy that matter has because of its location or structure
Electron shell
An electron’s state of potential energy (energy level), determines chemical behavior via distribution
Valence electrons
Those in the outermost shell / valence shell, heavily determines chemical behavior
Orbital
Three-dimensional space where electron is found 90% of the time
Chemical bonds
Atoms with incomplete valence shells can share or transfer valence electrons with certain other atoms, resulting in atoms staying close together
Covalent bond
The sharing of a pair of valence electrons by two atoms; the shared electrons count as part of each atom’s valence shell; can form between atoms of any kind
Molecule
Consists of two or more atoms held together by covalent bonds
Electronegativity
an atom’s attraction for the electrons in a covalent bond; more electronegativity -> stronger attraction
Nonpolar covalent bond
Atoms share electron equally
Polar covalent bond
Atoms share electron unequally, causing partial charge for each atom or molecule
Ion
A charged atom or molecule
An ionic bond
an attraction between an anion and a cation
Ionic compounds
compounds formed by ionic bonds or salts
Hydrogen bond
Forms when a hydrogen atom covalently bonded to one electronegative atom is also attracted to another electronegative atom
Van der Waals interactions
attractions between molecules that are close together as a result of charges
Chemical reactions
The making and breaking of chemical bonds
Reactants
Starting molecule of a chemical reaction
Products
Final molecules of a chemical reaction
Chemical equilibrium
reached when the forward and reverse reactions occur at the same rate
In the water molecule
The electrons of the polar covalent bonds spend more time near the oxygen than the hydrogen, making water a polar molecule with overall charge unevenly distributed; this allows water to form hydrogen bonds
Cohesion
Hydrogen bonds hold water molecules together
Adhesion
the attraction between different substances, for example, between water and plant cell walls
Surface tension
A measure of how difficult it is to break the surface of a liquid
Water has an
usually high surface tension due to hydrogen bonding
Kinetic energy
the energy of motion
Temperature
the average kinetic energy of the molecules in a body of matter
Heat
Thermal energy transferred from one body of matter to another, which is random motion of atoms or molecules
Calorie
Amount of heat to raise the temperature of 1 g of water by 1 C
Specific heat
The amount of heat that must be absorbed or lost for 1 g of that substance to change its temperature by 1 C
Water’s high specific heat
Heat is absorbed when hydrogen bonds break, heat is released when hydrogen bonds form
Heat of vaporization
The heat a liquid must absorb for 1 g to be converted to gas
Ice floats in liquid water because
Hydrogen bonds in ice are more “ordered”, making ice less dense than water
Solution
a liquid that is completely homogenous mixture of substances
SOLVENT
DISSOLVING AGENT
Solute
substance that is dissolved
Aqueous solution
One in which water is the solvent
Hydration shell
When an ionic compound is dissolved in water, each ion is surrounded by a sphere of water molecules
Molarity
The number of moles of solute per liter of solution
Hydrogen ion
the hydrogen atom that leaves it electron behind and becomes a proton
Hydroxide ion
the molecule that lost the proton
Hydronium ion
The molecule with the extra proton
Acid
Increases the H concentration; ph value less than 7
Base
reduces the H concentration; ph value greater than 7
Strong acids and bases
dissociate completely in water
Buffers
substances that minimize changes in concentration of H and OH
Dehydration reaction
Two monomers bond together through the loss of water molecule
Hydrolysis
Polymers are disassembled to monomers by adding water
Starch
A storage polysaccharide of plants, consists of glucose monomers <- Carbohydrate
Glycogen
A storage polysaccharide in animals
Cellulose
A major component of the tough wall of plant cells
Chitin
found in the exoskeleton of arthropods
Lipids
hydrophobic, does not include true polymers
Unsaturated and Saturated
Liquid (BENT), Solid
Amino acids
monomers that create polypeptides that are linked by covalent bonds called peptide bonds
Gene expression
DNA directs synthesis of mRNA to control protein synthesis
Nucleic acids
polymers called polynucleotides which are made up of nitrogenous base, a pentose sugar, and one or more phosphate group
Pyrimindines
Cytosine, Thymine, and Uracil (SMALLER)
Purines
Adenine and guanine (LARGER)
DNA Backbones
Run in opposite 5 to 3, antiparallel