alcohols

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16 Terms

1
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What are the two types of OH groups

Two OH groups - diol

Three- triol

2
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What conditions is ethanol made in

Aneorobic

35 degrees

3
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How is alcohol produced from alkenes?

Alkenes + H₂O (with phosphoric acid catalyst and steam). OH is added from water to form alcohols. The other H+ left as hydroxide ion

4
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What is the acid-catalyzed mechanism for ethene hydration?

H⁺ (from H₃PO₄)attacks ethene’s double bond.

2. Carbocation forms.

3. H₂O binds.

4. ethanol and H+ left

5
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fermentation equation for ethanol

C₆H₁₂O₆(aq) → 2C₂H₅OH(aq) + 2CO₂(g)

6
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Why is fermentation done anaerobically

To prevent oxidation of ethanol to ethanoic acid. O₂ would also inhibit yeast enzymes.

7
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What are the ethical issues of biofuel ethanol

Farmland used for fuel instead of food

Decrease bio diversity

Non renewable

8
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Is biofuel ethanol carbon-neutral

yes but doesnt account CO₂ from production/transport

9
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OH attached to 2 other carbons is

secondary

10
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What is dehydration of alcohols? Give conditions.

Removal of –OH + H to form alkene + H₂O.

Conditions: Reflux with H₂SO₄/H₃PO₄ catalyst.

11
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What products form from the oxidation of primary alcohols?

  • Partial oxidation: Aldehyde

  • Full oxidation: Carboxylic acid
    Oxidizing agent: Acidified K2Cr2O7 (orange → green).

12
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What are the oxidation products of primary alcohols?

Ol → al→oic Acid

13
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Why is phosphoric acid used in alkene hydration

It’s a strong acid catalyst that provides H⁺ to start the reaction.

14
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What is the stability order for carbocations

Tertiary > secondary > primary

15
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What is the role of yeast in fermentation

Yeast enzymes break down glucose into ethanol + CO₂ for energy (anaerobic respiration)

16
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How can you test for an alcohol’s class (primary/secondary/tertiary)

Oxidation test: Primary/secondary react with K₂Cr₂O₇ (orange→green)

tertiary does not