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conformational
same MF, same connectivity, different spatial
rotation around sigma bond
structural (constitutional)
same MF, different connectivity
ex: ring —> line
enantiomers
same MF, same connectivity, mirror images
have opposite R, S (all)
diastereomers
same MF, same connectivity, NOT mirror images
share at least one (but not all) R,S; or differ in E,Z
geometric
E/Z or cis/trans
tautomers
same MF, different connectivity (aka constitutional)