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Types of Weathering
Physical/Mechanical
Chemical
Mechanical Weathering processes
Breaking down rocks into smaller pieces without changing their chemical composition.
Freeze-thaw (ice wedging).
Thermal expansion due to change in temperature.
Plants and animals
Chemical Weathering processes
Air, Water, Carbonic Acid
Carbonic acid
Air pollutants (sulfuric and nitric)
What can happen during mineral weathering chemically?
Mineral = new weathered mineral + ions in solution
Mineral = ions in solution (salt and water)
Enhanced rock weathering (ERW)
Treating fields with ground basalt
Spreading crushed silicate rocks to accelerate weathering and draw CO₂..
Divalent cations
(2+; Ca, Mg) consume 2 molecules of CO₂ when weathering.
Monovalent cations
(1+; K, Na) consume 1 molecule of CO2 when weathering.
Susceptibility to chemical weathering
Least Stable - weather fast
Most stable weather slowly
Differential weathering
Different rocks, different resistance
Chemical composition and mechanical strength
Weathering
The physical breakdown and chemical alteration of rock at or near Earth’s surface.
Erosion
The physical removal of material by mobile agents such as water, wind, ice, or gravity.
Freeze-thaw (Ice Wedging)
Mechanical, caused by repeated freezing and thawing of water in cracks and pores.
Thermal Expansion
Mechanical processes repeated daily or seasonal heating and cooling of rocks causing them to break and crack.
Biological Weathering
Caused by activities of living organisms such as plant roots or burrowing animals.
H2O + CO2 → H2CO3
Water reacts with carbon dioxide to form carbonic acid, a weak acid that weathers many minerals.
Outcomes of Chemical Weathering
Transformation into residual mineral plus ions in solution
Complete dissolution into ions in solution.
Oxidation
Chemical weathering, where iron-rich material reacts with oxygen to form oxides, like rust.
Example of Oxidation
Transformation of Olivine (Fe₆SiO₄) into hematite (Fe₂O₃)
Solution (Dissolution)
Chemical weathering in which minerals dissolve in water, effective on carbonates like limestone.
Chemical Equation for limestone
(CaCO₃ + H₂CO₃ → Ca²⁺ + 2HCO₃⁻). Calcite reacts with carbonic acid to form calcium and bicarbonate ions.
Most stable mineral against chemical weathering.
Quartz.
Least stable mineral against chemical weathering
Olivine.
Relationship between mineral stability and crystallization.
Crystallized at high temperature, generally less stable and weather faster.
Differential Weathering
Rock masses weather at different rates, often creating uneven surfaces.
Strong mechanical weathering
Cold temp, and moderate precipitation
Strong Chemical weathering
Hot temp and high rainfall.
Karst Topography
Formed from the dissolution of soluble rocks characterized by sinkholes, caves, and drainage systems.
Mass Wasting
Downslope movement of rock, regolith, and soil under the direct influence of gravity.
Key factors driving mass wasting
Steepness of slope, presence of water, vegetation, shocks, and the properties of rock/soil.