Honors Chemistry - Unit 3 - Matter & Atomic Theory

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109 Terms

1
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What are allotropes?

A different form of an element

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What are the allotropes for oxygen?

Oxygen Gas, Ozone

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What is the chemical formula for oxygen gas?

O2

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What is the chemical formula for ozone?

O3

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What are the allotropes for carbon?

Graphite, Diamond and Buckminsterfullerene

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Name the 1st law of the atomic theory

Law of Definite Proportions

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Definition of the Law of Definite Proportions

Any sample of a compound always has the same composition 

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Example of the Law of Definite Proportions

Water is ALWAYS 11.2% hydrogen (H) and 88.8% oxygen (O)

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Name the 2nd law of the atomic theory 

Law of Conservation of Mass

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Definition of the Law of Conservation of Mass

Matter cannot be created or destroyed, only transformed

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Example of the Law of Conservation of Mass

Sulfur (S) (32.07g) + Oxygen (O2) (32.00g) → Sulfur Dioxide (SO2) (64.07g)

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Name the 3rd law of the atomic theory 

Law of Multiple Proportions

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Definition of the Law of Multiple Proportions

Different compounds have different mass proportions

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Example of the Law of Multiple Proportions

N2O = (N)(N)(O) … NO2 = (O)(N)(O)

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What did Democritis of Ancient Greece discover?

The idea that all matter is composed of atoms

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At the time in 400 BC when Democritis discovered the composition of atoms, was it really science?

No, it was a philosophy

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What does the word “Atom” come from?

The Greek word, “Atomos”

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What does Atomos mean?

Uncuttable

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What did John Dalton discover?

The 1st Atomic Theory (based on actual evidence)

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  1. All matter is made of indivisible atoms

Yes and no 

21
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  1. All atoms of an element are identical

Yes and no 

22
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  1. Atoms of different elements have different physical and chemical properties

Yes

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  1. Atoms of different elements combine in simple, whole number ratios to form compounds

Yes

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  1. Chemical reactions consist of the combination, separation and rearrangement of atoms

Yes

25
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What was Dalton’s atom like?

A marble

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Why was Dalton’s atom like a marble?

  1. Indivisible (no different paths)

  2. Indestructible

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Was Dalton correct about his marble theory regarding atoms?

Yes and no

28
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Why was Dalton correct and incorrect about his marble theory regarding atoms?

Scientific theories change with new evidence

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What did JJ Thomson discover?

The electron, the first subatomic particle

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How did JJ Thomson discover electrons?

Through using a cathode ray tube.

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What did Thomson discover about the “light” inside of the cathode ray tube? 

“Light” was affected by a magnet/charged plates (attracted to +, repelled by, -)

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How did Thomson calculate the mass of the particles?

He used the charge to mass ratio.

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Within the cathode ray tube, what types of metals/gases gave the same exact results?

Different types

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What charge do electrons have

negative

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What was Thomson’s conclusion?

“The atom is not indivisible, the atom consists of smaller particles

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If atoms are neutral, then there…

must be something positive inside the atom to balance the charge

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What was Thomson’s atom called?

Plum Pudding Model

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Describe the plum pudding model

The electrons were embedded a sphere of positive charged

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What did Ernest Rutherford discover?

Nucleus of an Atom

40
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What was Rutherfords’ Gold Foil Experiment?

involved firing alpha particles at a thin gold foil, expecting most to pass through with minimal deflection. However, the unexpected finding was that a small fraction of particles were deflected at large angles, and a few even bounced back.

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What are alpha particles?

massive, positively charged particles released by radioactive materials.

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What was expected of the Gold Foil Experiment?

Expected most alpha particles to pass through gold foil with minimal deflection

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Why did Rutherford expect for alpha particles to pass through gold foil with minimal deflection?

Plum pudding model was the accepted model at the time (positive charge was too diffuse)

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What were the actual results of Rutherford’s experiment?

1 in 8000 alpha particles deflected back

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Why did 1 in 8000 alpha particles bounce back?

  1. The alpha particle shit something that was positively charged, massive, and took up very little space (volume)

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What does Rutherford’s nuclear atom look like?

The nucleus is positively charged, most of the atom’s mass, tiny part of an atom’s volume,

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What is the density of the nucleus of the atom

(2.3 × 10^14 g/cm³)

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The atom is mostly…?

Empty space!

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If the atom were a size of Soldier Field, then the nucleus would be as big as…

A marble on the 50 yard line…

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Did John Dalton, JJ Thomson, or Ernest Rutherford have a good understanding of electrons?

No!

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What was Dalton’s conclusion on electrons?

“What’s an electron?”

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What was Thomson’s conclusion on electrons?

“Electrons are embedded in a sphere of positive charge”

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What was Rutherfords’s conclusion on electrons?

“Electrons are like planets around a star”

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What is the modern atom like?

A nucleus with protons and neutrons inside of an electron cloud with electron particles.

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What is the size of the nucleus of an atom

10^-13 cm

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What is the size of an atom

10^-8 cm

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What are the 3 different subatomic particles within an atom?

  1. Electron

  2. Proton

  3. Neutron

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What charge does an electron have 

-1 charge 

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What charge does an proton have 

+1 charge

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What charge does an neutron have 

neutral charge

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What is the mass of an electron

0.000549 = 0

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What is the mass of an proton

1.007276 = 0

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What is the mass of an neutron

1.008665 = 1

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Where is the electron located in the atom?

Electron cloud

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Where is the proton located in the atom?

Nucleus

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Where is the neutron located in the atom?

Nucleus

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Definition of Isotopes

Atoms with the same # of protons BUT different # of neutrons

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What does the symbol “p+” stand for?

Proton

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What does the symbol, “e-” stand for?

Electron

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What does the symbol, “n0” stand for?

Neutron

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How does one find the Proton #?

Proton # = Atomic #

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How does one find the Electron # of a NEUTRAL ATOM?

Electron # = Protons #

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What is a charged atom

Ion

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What is a positively charged ion

Cation

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What is a negatively charged ion

Anion

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How does one find the Electron # of a POSITIVELY CHARGED ION?

Electron # = Proton # - positive charge.

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How does one find the Electron # of a NEGATIVELY CHARGED ION?

Electron # = Proton # + negative charge. 

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How does one find the Neutron #?

Neutron # = Mass # - Proton #

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How does one find the Average Atom Mass #?

Average Atom Mass # = Proton # + Neutron #

80
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All matter is made of…

tiny, little particles

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Atom

basic unit of matter

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How many different types of atoms are there

118

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What is an element?

simplest substance, made only 1 type of atom

symbols (1 or 2 letters, watch your capitalization)

84
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Examples of elements

Oxygen (O), Hydrogen (H), Nitrogen (N), etc.

85
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The universe is exactly how much of H (hydrogen)?

90%

86
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Living things are made mostly out of what 4 elements?

  1. Oxygen (64%)

  2. Carbon (18%)

  3. Hydrogen (10%)

  4. Nitrogen (3%)

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When you hear organic, think…

carbon!

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What is a compound?

compound of at least 2 different atoms bonded together

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Examples of compounds

Caffeine (C8 H10 N4 O2), Table Salt (Sodium Chloride) (NaCl)

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Elements & compounds are what kind of substances?

Pure

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What does it meant when elements and compounds have a pure substance?

They have a constant composition.

92
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What is a mixture?

2 or more pure substances physically mixed together (not bonded)

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What is a homogeneous mixture

Components are uniformly distributed (looks the same throughout)

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Examples of homogeneous mixtures 

Salt water, Air, 14 karat gold

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What is another name for a homogeneous mixture?

Solution!

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What is a heterogeneous mixture

Components are not evenly distributed (you can see the different components)

97
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Examples of heterogeneous mixtures

Oil & water, orange juice, blood

98
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What is distillation?

Separation technique of a liquid mixture that depends on a difference in boiling points.

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What mixture does distillation work for?

Homogeneous mixtures

100
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What is filtration?

Separation technique of a heterogeneous mixture