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Rutherord- atoms were mostly empty space
with small, dense positively charged nucleus.
Bohr Model - Small, dense, positively
charged nucleus surrounded by electrons in circular orbits.
Protons and neutrons are found
in the nucleus.
The number of protons in an atom equals
the number of electrons.
The mass of a proton and nuetron is
1 amu
The mass of an electron
n is almost 0 amu.
Each electron in an atom has its own distinct amount of
energy
. The outermost electrons are called
valence electrons.
atoms with equal numbers of protons but different numbers of neutrons
are called isotopes
The average atomic mass of an element is the
weighted average of its naturally occurring isotopes.
Transmutation
A change in the nucleus of an atom changes it to a new type of atom
Spontaneous decay can involve the release of different particles from the
nucleus
Chemical compounds are formed when
atoms are bonded together.
Ionic substances have
high melting and boiling points, form crystals, dissolve in water (dissociation), and conduct electricity in solution and as a liquid.
Covalent or molecular substances have
lower melting and boiling points, do not conduct electricity
. Chemical bonds are formed when valence electrons are
ionic,covalent, and metallic
In multiple (double or triple) covalent bonds more than
1 pair of electrons are shared between two atoms.
Polarity of a molecule can be determined by its
shape and the distribution of the charge.
When an atom loses an electron
it becomes a positive ion and its radius decreases.
When an atom gains an electron,
it becomes a negative ion and its radius increases.
. Electronegativity indicates
how strongly an atom of an element attracts electrons in a chemical bond. These values are based on an arbitrary scale.
0.0 - 0.4 =
non-polar covalent
0.4-1.7 =
polar covalent
1.7+ =
ionic
Metals react with nonmetals to form
ionic compounds.
Nonmetals bond with nonmetals to form
covalent compounds (molecules).
Ionic compounds with polyatomic ions have
both ionic and covalent bonds.
Filtration and distillation are examples of processes used to
separate mixtures.
. Heat of fusion (Hf)is
the energy needed to convert one gram of a substance from solid to liquid.
Heat of vaporization (Hv) is the
energy needed to convert one gram of a substance from liquid to gas.
Increasing pressure causes
a decrease in volume
Increasing temperature causes an
increase in volume
Increasing temperature causes
an increase in pressure.
A real gas is most like an ideal gas when
it is at low temperature and high pressure.
Equal volumes of gasses at the same temp and pressure
have an equal number of particles.
The Law of Conservation of Energy states that energy can not be
lost or destroyed, only changed from one form to another.
Temperature is
a measure of the average kinetic energy of the particles in a sample
Elements are arranged in order of increasing
atomic number.
The atomic mass is the sum of
protons and neutrons in the nucleus
Isotopes of an element are identified by
the sum of protons and neutrons.
Isotopes of the same element have the
same number of protons and a different number of neutrons.
. Elements may be differentiated by
their physical n chemical properties
Ex of physical: Density, conductivity, malleability, hardness, ductility, solubility
Elements of the same period
have the same number of occupied energy levels.
Group 1 elements other than H
alkali metals.
Group 2 elements
alkali earth metals.
Group 17 elements are
halogens.
Group 18 elements are
noble or inert gasses
All chemical reactions show
a conservation of mass, energy and charge.
A balanced chemical equation represents
conservation of atoms.
Solubility depends on
temperature, pressure, and the nature of the solute and solvent.
2. Ionic substances dissolve
in polar solvents.
Adding a solute to a solvent causes the boiling point of the solvent to ___ and the freezing point to _____
Increase
decrease
. Collision theory states that a reaction is most likely to occur
if reactant particles collide with the proper energy and orientation.
At equilibrium the rate of the forward reaction equals
the rate of the reverse reaction.
A catalyst provides an alternative pathway for a chemical reaction
The catalyzed reaction requires a lower activation energy than the uncatalyzed reaction.
Adding a catalyst increases the rate of the forward and reverse reactions equally,
there is no shift in equilibrium.
Entropy is a measure of the
randomness or disorder in a system.
Exothermic reactions that result in increased entropy are
spontaneous.
Arrhenius acids and bases
are electrolytes.
electrolyte
substance which, when dissolved in water, forms a solution capable of conducting electricity
In neutralization
reactions an Arrhenius acid and an Arrhenius base react to form salt and water.
an acid is an
H+ donor
a base an
H+ acceptor.
An oxidation-reduction (redox) reaction involves
the transfer of electrons (e- ).
Reduction is the
gain of electrons and decrease of oxidation number.
. Oxidation is the
loss of electrons and increase of oxidation number.
An electrochemical cell can be either
voltaic or electrolytic.
In an electrochemical cell oxidation occurs
at the anode and reduction at the cathode.
electrolysis.
. An electrolytic cell requires energy to produce a chemical change
6. Isomers of organic compounds have
the same molecular formula but different structures and properties.