chem regents

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84 Terms

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Rutherord- atoms were mostly empty space

with small, dense positively charged nucleus.

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Bohr Model - Small, dense, positively

charged nucleus surrounded by electrons in circular orbits.

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Protons and neutrons are found

in the nucleus.

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The number of protons in an atom equals

the number of electrons.

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The mass of a proton and nuetron is

1 amu

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The mass of an electron

n is almost 0 amu.

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Each electron in an atom has its own distinct amount of

energy

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. The outermost electrons are called

valence electrons.

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atoms with equal numbers of protons but different numbers of neutrons

are called isotopes

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The average atomic mass of an element is the

weighted average of its naturally occurring isotopes.

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Transmutation

A change in the nucleus of an atom changes it to a new type of atom

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Spontaneous decay can involve the release of different particles from the

nucleus

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Chemical compounds are formed when

atoms are bonded together.

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Ionic substances have

high melting and boiling points, form crystals, dissolve in water (dissociation), and conduct electricity in solution and as a liquid.

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Covalent or molecular substances have

lower melting and boiling points, do not conduct electricity

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. Chemical bonds are formed when valence electrons are

ionic,covalent, and metallic

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In multiple (double or triple) covalent bonds more than

1 pair of electrons are shared between two atoms.

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Polarity of a molecule can be determined by its

shape and the distribution of the charge.

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When an atom loses an electron

it becomes a positive ion and its radius decreases.

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When an atom gains an electron,

it becomes a negative ion and its radius increases.

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. Electronegativity indicates

how strongly an atom of an element attracts electrons in a chemical bond. These values are based on an arbitrary scale.

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0.0 - 0.4 =

non-polar covalent

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0.4-1.7 =

polar covalent

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1.7+ =

ionic

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Metals react with nonmetals to form

ionic compounds.

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Nonmetals bond with nonmetals to form

covalent compounds (molecules).

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Ionic compounds with polyatomic ions have

both ionic and covalent bonds.

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 Filtration and distillation are examples of processes used to

separate mixtures.

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. Heat of fusion (Hf)is

the energy needed to convert one gram of a substance from solid to liquid.

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Heat of vaporization (Hv) is the

energy needed to convert one gram of a substance from liquid to gas.

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Increasing pressure causes

a decrease in volume

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Increasing temperature causes an

increase in volume

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Increasing temperature causes

an increase in pressure.

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A real gas is most like an ideal gas when

it is at low temperature and high pressure.

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Equal volumes of gasses at the same temp and pressure

have an equal number of particles.

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The Law of Conservation of Energy states that energy can not be

lost or destroyed, only changed from one form to another.

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Temperature is

a measure of the average kinetic energy of the particles in a sample

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Elements are arranged in order of increasing

atomic number.

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The atomic mass is the sum of

protons and neutrons in the nucleus

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Isotopes of an element are identified by

the sum of protons and neutrons.

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Isotopes of the same element have the

same number of protons and a different number of neutrons.

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. Elements may be differentiated by

their physical n chemical properties

Ex of physical: Density, conductivity, malleability, hardness, ductility, solubility

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Elements of the same period

have the same number of occupied energy levels.

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Group 1 elements other than H

alkali metals.

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Group 2 elements

alkali earth metals.

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Group 17 elements are

halogens.

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Group 18 elements are

noble or inert gasses

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All chemical reactions show

a conservation of mass, energy and charge.

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A balanced chemical equation represents

conservation of atoms.

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Solubility depends on

temperature, pressure, and the nature of the solute and solvent.

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2. Ionic substances dissolve

in polar solvents.

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Adding a solute to a solvent causes the boiling point of the solvent to ___ and the freezing point to _____

Increase

decrease

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. Collision theory states that a reaction is most likely to occur

if reactant particles collide with the proper energy and orientation.

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At equilibrium the rate of the forward reaction equals

the rate of the reverse reaction.

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A catalyst provides an alternative pathway for a chemical reaction

The catalyzed reaction requires a lower activation energy than the uncatalyzed reaction.

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 Adding a catalyst increases the rate of the forward and reverse reactions equally,

there is no shift in equilibrium.

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Entropy is a measure of the

randomness or disorder in a system.

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Exothermic reactions that result in increased entropy are

spontaneous.

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Arrhenius acids and bases

are electrolytes.

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electrolyte

substance which, when dissolved in water, forms a solution capable of conducting electricity

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In neutralization

reactions an Arrhenius acid and an Arrhenius base react to form salt and water.

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an acid is an

H+ donor

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a base an

H+ acceptor.

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An oxidation-reduction (redox) reaction involves

the transfer of electrons (e- ).

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Reduction is the

gain of electrons and decrease of oxidation number.

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. Oxidation is the

loss of electrons and increase of oxidation number.

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An electrochemical cell can be either

voltaic or electrolytic.

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In an electrochemical cell oxidation occurs

at the anode and reduction at the cathode.

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electrolysis.

. An electrolytic cell requires energy to produce a chemical change

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6. Isomers of organic compounds have

the same molecular formula but different structures and properties.

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