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Relative atomic mass (Ar)
Average mass of an atom of an element
1/12 mass of one atom of C12
Contains 1 mole of atoms
Formula for moles
Moles = mass / mr
Formula for concentration
Conc= mass/volume Or conc= moles/volume
Mass= g
Volume= dm³
Empirical formula
Simplest whole number ratio of atoms of each element in a compound
Molecular formula
Actual number of atoms of each element in a compound
A hydrocarbon contains 1.2g of carbon and 0.4g of hydrogen. What is the empirical formula?
Carbon Hydrogen
Mass 1.2 0.4
Ar 12.0 1.0
Moles 1.2/12=0.1 0.4/1.0=0.4
Mole ratio 1 : 4
=CH4
Water of crystallisation
Water found in a crystalline framework of an ionic compound
CuSO4 . XH2O
Hydrated copper sulfate mass= 6.864g
Anhydrous copper sulfate mass= 4.389g
Find X
Mass of water loss= 6.864-4.389=2.475
Moles of CuSO4:
Moles=mass/mr
4.389/159.6=0.0275
Moles of water:
Moles=mass/mr
2.475/18.0=0.138
0.1375/0.0275=5
1:5
So CuSO4 . 5H2O
Law of conservation of mass
Atoms cannot be created or destroyed, only reorganised
Charges on NH4 , OH , NO3 , SO4, CO3 , PO4
Ammonium- NH4 1+
Hydroxide- OH-
Nitrate- NO3 1-
Sulfate SO4 2-
Carbonate- CO3 2-
Phosphate- PO4 3-
Ideal gas equation
pV= n R T
Pressure is Pa (pascals)
Volume is m³
R (universal gas constant) 8.31 J K-1 Mol-1
How many kPa is 1 atmosphere (atm)
101 kPa = 1 atmosphere (atm)
Convert Celsius to kelvin
Celsius + 273 = K
Volume conversion from cm³ to m³
Cm³ → m³ Divide by 1,000,000 or 10^6
Limiting factor
Chemical that gets used up
Excess
More than enough of this chemical, will be some left over
Theoretical yield (max yield)
Largest amount of product that could be made (assuming no problems)
Actual yield
Amount of product you make in an experiment (usually less than theoretical yield, CANNOT be bigger)
Percentage yield
Actual yield/ theoretical yield x 100
Mass produced/ max mass possible x 100
Moles produced/ theoretical moles x 100