Identify Halides

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6 Terms

1
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Why does Halides need to be dissolved in water ?

To release ions , breaking the ionic bond

NaI ( s ) → Na+ ( aq ) + I - ( aq)

2
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Why add Nitric acid hNO3 acid to halides ?

To remove hydroxide ion or carbonate ion that might interfere with the test

3
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Why add sliver nitrate solution AgNO3

To form sliver halide precipitate

Ag+ ( aq ) + I - ( aq) → AgI ( g )

4
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What is the identification

White ppt : Cl-

Cream ppt : Br-

Yellow ppt : I-

5
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What can you do to make it easier to distinguish them ?

Divide sample into 2.

1 add dilute ammonia 1 add concentrated ammonia

6
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Identification

Cl- : dissolved in both

Br- : only dissolved in concentrated ammonia

I- : Insoluble