Chemical Equilibria

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21 Terms

1
Le Châteliers Principle
________: when a chemical system at equilibrium is disturbed, it returns to equilibrium by counteracting the disturbance.
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2
Solids
________ are always omitted from the expressions for Q and K.
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3
K
An increase in temperature will change K. It will increase ________ for an endothermic, and decrease ________ for an exothermic.
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4
chemical equilibrium
If a(n) ________ is disturbed by adding a reactant or product, the system will proceed in the direction that consumes part of the added species.
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5
Qc
________ can be calculated at any point in a reaction.
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6
Homogenous equilibrium
________: one in which all of the reactants and products are present in the same phase.
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7
Heterogenous equilibria
________: contain reactants and products that are in two or more different phases.
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8
concentration of products
The value of Qc depends on the ________ and reactants present at that particular moment.
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9
Equilibrium constant
________ (K): the value of Q when the reaction is at equilibrium.
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10
reversible reactions
For ________, catalysts increase the rates of the forward and ________.
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11
gas phase solutions
For ________, the equilibrium constant may be expressed in terms of either the molar concentrations (Kc) or partial pressures (Kp) of the reactants and products.
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12
SOLID
If what is added or removed is a(n) ________ or liquid, the reaction does not shift at all.
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13
K
If ________ is very small, the mixture contains mostly reactants at equilibrium.
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14
Equilibrium constant (K)
the value of Q when the reaction is at equilibrium
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15
When Q < K*
* reaction must shift FORWARD
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16
When Q > K*
* reaction must shift BACKWARD
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17
When Q = K*
* reaction is at equilibrium, and will maintain constant concentration
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18
Homogenous equilibrium
one in which all of the reactants and products are present in the same phase
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19
Heterogenous equilibria
contain reactants and products that are in two or more different phases
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20
Le Châteliers Principle
when a chemical system at equilibrium is disturbed, it returns to equilibrium by counteracting the disturbance
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21
Result
A catalyst causes the system to reach equilibrium more quickly
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