Biomolecules

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204 Terms

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Biomolecules

All the organic compounds/molecules that can be obtained from a living cell/tissue/organism

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The relative abundance of Carbon and Hydrogen is…

higher in living beings than in Earth’s crust

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Chemical composition analysis in living tissue

Grind the trichloroacetic acid with the living tissue and strain through a cloth to form 2 compounds: a filtrate(acid-soluble) and a retentate(acid-insoluble)

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Micromolecules and what they include

Molecules weighed less than 1000 daltons and present in acid-soluble pools. Include amino acids, N bases, and monosacharides

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Macromolecules

Molecules weighing more than 1000 daltons and present in acid-insoluble pools. Include proteins, nucleic acids, polysacharides

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“Ash” analysis technique

Drying a living tissue and burning it too be left with inorganic compounds to study the chemical analysis of living tissue

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Abundance of elements from greatest to lowest in the human body

O > C > H > N

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Abundance of elements from greatest to lowest in the Earth’s crust

O > Si > Ca > Na

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Metabolites

intermediate products of metabolism

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Primary metabolites

metabolites required for basic or primary metabolic processes

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Secondary metabolites

metabolites not involved in primary metabolism and have no direct function in growth and development.

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Examples of secondary pigment metabolites

Carotenoids & Anthocyanins

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Examples of secondary alkaloid metabolites

Morphine & Codeine

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Examples of secondary terpenoid metabolites

Monoterpenoid & Diterpenoid

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Examples of secondary essential oil metabolites

lemon grass oil, rosemary oil

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Examples of secondary toxin metabolites

Abrin & Ricin

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Examples of secondary lectin metabolites

Concanavalin A

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Examples of secondary drug metabolites

Vinblastin & Circumin

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Examples of secondary polymeric metabolites

Rubber, Gums, cellulose

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The four micromolecules are…

Proteins, Nucleic Acids, Carbohydrates, and Lipids

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Polymeric substances

Any substances which are in the form of a polymer or are found as a polymer

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Water is the…

most abundant chemical in all living organisms

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What are carbohydrates?

They are the main source of energy and the cell’s first choice of energy made of monosachhcarides.

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Carbohydrate ratio

Carbon, hydrogen, and oxygen in a 1:2:1 ratio

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Polyhydroxy aldehydes or ketones

Chemical compostion of carbohydrates

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Monosaccharides

The simplest sugars which cannot be furthur broken down, all occur in both the D & L form except Dihydroxyacetone, and in either a ring or straight chain.

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All monosaccharides are…

poly-hydroxy aldehydes or ketones

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Chiral Carbon

A carbon atom that is attached to four different types of atoms or group of atoms

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Pyranose

6-carbon ring

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Furanose

5-carbon ring

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Anomers

type of monosaccharides that have the -H and -OH groups changing at the anomeric carbon in only cyclic forms.

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Anomeric carbon

aldehyde or ketone carbon which connects the linear form to the cyclic form

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Epimers

isomers formed as a result of intechange of the -OH and -H groups on just one carbon atoms. Exist in both linear and cyclic forms.

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Aldoses

monosaccharides with free aldehyde groups

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Ketones

monosaccharides with free ketone groups

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Trioses

3-carbon monosaccharide (C3H603) - Dihydroxyacetone, glyceraldehyde

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Tetroses

4-carbon monosaccharides (C4H8O4) - Erythrose and Erythrulose

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Pentoses

5-carbon monosaccharides (C5H10O5) - xylose, xylulose, deoxyribose, aribonose, ribose, ribulose

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Hexoses

6-carbon monosaccharides (C6H12O6) - glucose, fructose, galactose, mannose

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Heptoses

7-carbon monosaccharides (C7H14O7) - seduheptulose

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Glucose

Main respiratory substance also known as grape sugar, blood sugar, and dextrose

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Fructose

Sweetest carbohydrate and also known as fruit sugar and laevulose

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Galactose

most abundant carbohydrate found in brain and nervous tissue so its also called brain sugar

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Mannose

Carbohydrate present in hemicellulose

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Oligosaccharides

Carbohydrates made of 2-10 monosaccharides linked when an aldehyde or ketone group fo one monosaccharide reacts with an alcoholic group of another monosaccharide to form a glycosidic linkage from 1’ to 4’

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Disaccharides

Carbohydrates composed of 2 monosaccharide units that are water soluble and sweet in taste.

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Maltose

disaccharide which is in intermediate compound in starch digestion and abundant in germinating starchy seeds (malt sugar)

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Lactose

Disaccharide also known as “milk sugar”

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Sucrose

Naturally non-reducing disaccharide which is used to transport sugars in plants. A.k.a invert sugar, cane sugar, or commercial sugar

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Trehalose

Naturally non-reducing disaccharides present in the haemolymph(insect blood) cof insects

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Polysaccharides

carbohydrates composed of a large number of monosaccharides that are insoluble in water and do not taste sweet

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Right end of polysacchardes

reducing end

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Left end of polysacchardes

non-reducing end

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Nutritive polysaccharides

carbohydrates present as stored food such as starch and glycogen

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Structural polysaccharides

carbohydrates used in structure formation

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Homopolysaccharides

polysaccharides composed of the same monomer

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Cellulose

Most abundant organic unbranched, linear homopolysaccharide of ß-d-glucose units at a ß 1’-4” linkage which is used as the main component of plant cell walls and to form Rayon fibre.

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Starch

Homopolysaccharides made of ⍺-D-glucose units used and composed of 20% amylose and 80% amylopectin to store food in plants and gives a blue colour with iodine solution

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Amylose

unbranched homopolysaccharides made up of less ⍺-D-glucose units at a 1’-4” linkage

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Amylopectin

branched homopolysaccharide made up of more ⍺-D-glucose units.

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Amylopecting branching occurs approx. …

every 20-30 ⍺-D-glucose units at 1’-4” & and 1’-6”

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Glycogen

highly branched homopolysaccharide of approx. 6 lakh ⍺-D-glucose units used as a storage form of carbohydrate in the liver and muscles of animals at

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Chitin

homopolysaccharide which is the linear polymer of N-acetyl-D-glucosamine and an important component of the exoskeleton of Arthropods and cell wall of fungi

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Inulin

smallest storage water-soluble homopolysaccharide of 25-35 fructose units linked by ß-1’-2” bonds found in the roots of Dahlia and Artichokes.

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Dextrin

intermediate homopolysaccharide obtained by the digestion of glycogen and starch and hydrolyzed to from maltose and glucose

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Heteropolysaccharides

polysaccharides composed of different monosaccharides

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Hyaluronic acid

heteropolysaccharides made of D-glucuronic acid and N-acetyl-D-glucosamine arranged alternately to form a binding material (animal cement)found in the extracellular matrix of connective tissue for its toughness and flexibility of cartilage and tendons

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Chondroitin

heteropolysaccharide which occurs in connective tissue

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Heparin

heteropolysaccharide which is an anticoagulant of blood

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Pectins

heteropolysaccharide found in cell walls where it binds cellulose fibres in bundles

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Hemicellulose

heteropolysaccharide present in cell wall

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Agar

mucopolysaccharide obtained from red algae to be used as a culture medium in laboratory

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Lipids

hydrophobic micromolecules that do not form polymers and provide more energy than carbohydrates stored as fats and its derivatives

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Simple Lipids

three long chain fatty acids and a glycerol bonded by an ester bond to form a tryglycerol

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Glycerol

a trihydroxy sugar alcohol or trihydroxy propane in tryglycerides

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Fatty acids

long chains with a carboxyl group and an R group which could be a methyl, ethyl, or a higher number of CH2 groups

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Triglycerides

simple lipid made by 3 fatty acid chains and a glycerol

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Saturated Fatty acid chains

Non-essential and less reactive fatty acids that are present in solid form due to the presence of only C-C single bonds and found in mostly in animals except fish.

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Unsaturated fatty acid chains

Essential highly reactive fatty acids that are present in a liquid form due to the presence of C-C double AND single bonds and are found in mostly plants and fish

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MUFA

monounsaturated fatty acid chains composed of 18-C Oleic acid

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PUFA

polyunsaturated fatty acid chains composed of 18-C Linoleic or 20-C Arachidonic acid

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Waxes

Monoesters with only one molecule of fatty acid attached to a monohydroxy alcohol

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Compound Lipids

lipids composed of phospholipids

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Phospholipids

Amphipathic lipids in the cell membrane composed of 2 molecules of fatty acid chains, 1 glycerol, H3PO4, and a nitrogenous compound.

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Amphipathic

Having hydrophobic tails and a hydrophilic tail

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Lecithin or Phosphatidyl choline

phospholipid attached to a nitrogeneous choline located in the cell membrane

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Cephalin

phospholipid attached to a nitrogenous Ethanolamine in nervous tissues, egg yolk, and blood platelets

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Sphingolipids

Phospholipids with an amino alcohol sphingosine instead of a glycerol at the myelin sheath of nerves

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Glycolipids

A compound lipid with one fatty acid, one sphingosine, and one galactose

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Gangliosides

these occur in nerve ganglia and spleen

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Derived Lipids

complex lipids derived from simple or compound lipids that are insoluble in water and soluble in organic solvents

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Steroids

derived lipids that exhibit tetracyclic structure and regulate organismal processes

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Sterols

Also known as cholesterol, it acts as the parent steroid and transforms into Cholecalciferol (Vitamin D0) when exposed to UV radiation

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Sterones

Ketonic steroids used as sex hormones such as testosterone and progesterone

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Chromolipid

most complex lipid in plasma membrane composed of repeated isoprene units

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Proteins

Macromolecules made from C, H, O, N, S and the heteropolymers to amino acids

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Structure of amino acid

Side group, one carboxyl, one hydrogen, and one alkaline compound bonded to a central carbon atom

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Amino acids

organic amphoteric compounds containing an amino group and an acidic group on the same carbon with substituted methanes

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Isoelectric point

point of pH where amino acids have both positive and negative charges in equal amounts

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Threonine

essential amino acids