Substituent Effects ACOC II

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Last updated 2:43 PM on 6/11/26
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15 Terms

1
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Alkyl

Sigma donor

2
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O-

Sigma donor, π-donor

3
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SiR3

Sigma donor

4
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GeR3

Sigma donor

5
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SnR3

Sigma donor

6
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-I < Br < Cl < F (Halogens)

Sigma acceptor, π-donor

7
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NR2 < OR < F < R3N+

Sigma acceptors, with NR2, OR and F also π-donors

8
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C=C < Ph < C TB C

Sigma acceptors, with Ph and C=C as π-donors

9
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SR

π-donor

10
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C=O

Is π-acceptor

11
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C=N-R

π-acceptor

12
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-C TB N

Is π-acceptor

13
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-NO2

Is π-acceptor

14
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SO2R

Is π-acceptor

15
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-S(=O)R

Is π-acceptor