Molecular Geometry and Lewis Structures

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Flashcards based on Molecular Geometry and Lewis Structures lecture notes.

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10 Terms

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ABnem

A = central atom, B = directly bonded atoms to A, and e = nonbonding (unshared) pairs of electrons in molecular geometry formula.

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Linear Molecular Geometry

Molecular geometry with 2 electron regions, 2 bonding regions, and 0 nonbonding regions, such as HgCl2 and CO2.

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Trigonal Planar Molecular Geometry

Molecular geometry with 3 electron regions, 3 bonding regions, and 0 nonbonding regions, such as BF3 and SO3.

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Bent Molecular Geometry

Molecular geometry with 3 electron regions, 2 bonding regions, and 1 nonbonding region, such as SO2 and NO2-.

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Tetrahedral Molecular Geometry

Molecular geometry with 4 electron regions, 4 bonding regions, and 0 nonbonding regions, such as CH4 and SiCl4.

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Trigonal Pyramidal Molecular Geometry

Molecular geometry with 4 electron regions, 3 bonding regions, and 1 nonbonding region, such as NH3 and PF3.

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Octet Rule

The principle that atoms are most stable with eight electrons in their valence shell (except for hydrogen, which is stable with two).

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Formal Charge

The charge assigned to an atom in a molecule, assuming that electrons in all chemical bonds are shared equally between atoms.

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Resonance

When multiple valid Lewis structures can be drawn for a molecule, representing different possible arrangements of electrons.

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Valence Electrons

The electrons in the outermost shell of an atom that participate in chemical bonding.