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When does VSEPR indicate point group
When all the ligands are the same
VSEPR structure indicates highest point group association but it can be less depending on the ligands bonded
Three atom linear
D(infinity h)
Bent
C(2v)
Trigonal Planar
D(3h)
Tetrahedral
T(d)
Trigonal Pyramidal
C(3v)
Trigonal Bipyramidal
D(3h)
See-Saw
C(2v)
T-Shaped
C(2v)
Octahedral
O(h)
Square Pyramidal
C(4v)
Square Planar
D(4h)
No symmetry elements
C1
Only inversion center
Ci
Only reflection plane
Cs