Addition Reactions Worksheet

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10 Terms

1

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hydrohalogenation

H,X

favors mark

racemic mixture

H-X

2

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hydrobromination

H-Br

favors anti-mark

racemic mixture

3

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Hydration

H,OH

favors mark

racemic

H2SO4 dilute

4

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Hydroboration Oxidation

BH3 THF

H2O2, NaOH

syn addition

favors anti mark

5

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Halogenation

X,X

makes two chiral centers

6

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Hydroxyhalogenation

OH,X

X2, H2O

7

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Hydrogenation

H2

typically mark

syn addition

8

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syn-dihydroxylation

catalytic OsO4

H2O

syn addition

9

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anti-dihydroxylation

mCPBA, H2O

anti addition

10

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ozonolysis

O3,DMS

breaks pi bond and replaces w/O