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Thermochemistry
the study of the energy and heat associated with chemical reactions
EXOthermic
gives out energy
ENDOthermic
takes in energy
Enthalpy Change
amount of energy transferred to and from the surroundings
negative enthalpy change
exothermic
positive enthalpy change
endothermic
What is enthalpy change affected by?
temperature
pressure
concentration
Standard Conditions
298K (25 C)
100kPa
1 mol dm-3
How to convert from Celsius to Kelvin?
add 273
Standard enthalpy change of reaction
The enthalpy change when molar quantities of reactants as stated in the equation react together under standard conditions.
specific heat capacity
The amount of energy needed to raise the temperature of 1 kg of substance by 1°C
q= mc/T
Standard enthalpy change of combustion
when one mole of substance in burned completely in oxygen under standard conditions in standard states
Standard enthalpy change of formation
when one mole of compound is formed from its elements under standard conditions in standard states
Standard enthalpy change of neutralisation
when one mole of hydrogen ions react with one mole of hydroxide ions under standard conditions and in solution containing 1 mol dm-3