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Vocabulary flashcards covering key terms and definitions from the notes on the photoelectric effect, electron collisions, energy levels, and wave–particle duality.
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Work function (φ)
Minimum energy required for an electron to escape from the surface of a metal.
Einstein’s photoelectric equation
hf = φ + E_k; the energy of the incoming photon equals the work function plus the kinetic energy of the emitted electron.
Threshold frequency (f0)
Minimum frequency of incident photons required to cause emission; determined by hf0 = φ.
Planck’s constant (h)
Proportionality constant relating energy and frequency: E = h f; h ≈ 6.63 × 10^-34 J·s.
Photon energy
Energy carried by a photon, given by E = h f.
Electron volt (eV)
Energy gained by an electron when moved through a potential difference of 1 volt; 1 eV = 1.6 × 10^-19 J.
Ionisation
Removal of an electron from an atom, producing a positively charged ion.
Excitation
Movement of an electron to a higher energy level within an atom.
Ways to excite electrons
Excitation can occur via collision with another electron or by absorbing a photon of the correct frequency.
Fluorescent tube
Contains mercury gas; accelerated electrons ionise mercury; UV photons are emitted and absorbed by a phosphor coating to emit visible light.
Phosphor coating
Inside a fluorescent tube; absorbs UV photons and re-emits visible light.
Line spectrum
A set of characteristic wavelengths emitted or absorbed by the atoms of an element.
Energy levels in atoms
Discrete energy levels; electrons transition between them, emitting or absorbing photons.
De-excitation
Transition of an electron from a higher to a lower energy level, emitting a photon.
Ground state
The lowest energy state of an atom (n = 1 for hydrogen).
De Broglie wavelength
Wavelength associated with a moving particle; λ = h/p (non-relativistic: p = mv).
Electron diffraction
Experiment showing the wave nature of electrons; produces a diffraction pattern similar to light.
Wave–particle duality
Concept that light and matter exhibit both wave-like and particle-like properties.
Four wave-like behaviours of light
Reflection, Refraction, Diffraction, and Interference.
Infrared region
Region of the electromagnetic spectrum with frequencies longer than visible light; example frequency around 2.6 × 10^14 Hz.
Photon
Quantum/particle description of light; a quantum of electromagnetic radiation.
Energy of a photon in a transition
The energy difference between two levels equals the energy of the emitted/absorbed photon: ΔE = h f.