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What was proven by the rutherford scattering experiment?
The existence of the nucleus
Describe JJ Thomson’s plum pudding model.
A sphere of positive charge with small areas of negative charge evenly distributed throughout
What is the name of the atomic model that arose from the scattering experiment?
Nuclear Model
Describe the process of the rutherford scattering experiment.
Alpha particles were fired at a thin piece of gold foil and the path of the alpha particles was observed on the walls of the vacuum chamber
What results were expected from the experiment?
Most particles would be deflected with only few passing through the foil
What results were actually observed from the experiment?
Most alpha particles passed through with no deflection
A small amount of particles deflected at a large angle
Very few particles were deflected back by more than 90*
What did most particles passing though the gold foil suggest?
Most of the atom is empty space
What did the deflections at large angles by the particles suggest?
The centre of the atom is positively charged
What did the fact that few particles were deflected more than 90* suggest about the atom?
The nucleus of the atom is very small and very dense (as it deflects fast moving alpha particles)
What is radiation?
When an unstable nucleus emits energy in the form of EM waves or subatomic particles in order to become more stable
Name the 3 types of radiation?
Alpha
Beta
Gamma
State the ranges of the 3 types of radiation.
Alpha - 2-10cm
Beta - 1m
Gamma - infinite
State the ionising power of the 3 types of radition.
Alpha - Highly
Beta - Weakly
Gamma - Very weakly
What are all types of radiation deflected by?
Electric and magnetic fields
What is alpha radiation absorbed by?
Paper
What is beta radiation absorbed by?
Aluminium foil
What is gamma radiation absorbed by?
Several metres of concrete of several inches of lead
Describe a simple experiment to determine the type of radiation produced by a source.
Use a GM counter to find the background radiation
Place the source next to the counter and measure the count rate
Place a sheet of paper between the source and counter and measure the count rate (if it decreases significantly, the source is an alpha emitter)
Repeat using foil and lead
How can beta radiation be used during the production of aluminium foil?
A beta source and counter are placed either side of the foil, if the foil become too thick, less beta radiation is detected and the rollers will press the foil more
Why is gamma radiation appropriate for use in medicine?
It is very weakly ionising so does far less damage then alpha and beta radiation
Describe 3 ways in which gamma radiation is used in medicine.
As a detector - gamma sources can be injected into a patient and cameras can be used to identify it and diagnose them
To sterilise surgical equipment - gamma radiation will kill any bacteria
Radiotherapy - gamma radiation can be used to kill cancerous cells in a targeted region of the body
What safety measures can be taken to reduce risk of radiation poisoning during gamma radiation therapy?
Reduced exposure times
Use of shielding
What law does the intensity of gamma radiation in air follow?
I = k/x²
Describe an experiment to verify that gamma radiation obeys the inverse square law.
Measure the count rate at different distances from the GM tube, making sure to account for background radiation
Plot a graph of corrected count against 1/x² - a straight line verifies the equation
Why is alpha radiation dangerous to humans?
It is highly ionising, so can damage and kill cells
Why is gamma radiation dangerous to humans?
Prolonged exposure can cause mutations and damage to body cells
What safety measures should be taken when handling radiation in a lab?
Use long handled tongs to move the source
Store in a lead-lined container
Keep as far as possible away from people
Do not point the source at others
What is background radiation?
Low-level radiation present in the atmosphere at all times
Where does background radiation come from?
Cosmic rays, radioactive elements in rocks and soil, medical X-rays, power plants, radon gas
State how to calculate the corrected count in an experiment.
Corrected count = total count rate - background count
Why is radioactive decay a random process?
It cannot be precited when the next decay will occur and which nucleus will decay
What is meant by the decay constant of a sample?
The probability of a nucleus decaying per unit time
State the equation for the decay constant.
change in N / change in t = -decay constant x N
State the formula for exponential radioactive decay.
N = N0e-^t
What is meant by half-life?
The time taken for the number of radioactive nuclei in a sample to halve
Describe how to determine half-life from a graph.
Find the time where the nuclei halves and then repeat, calculating a mean
What is a more accurate way of calculating half life from an experiment?
Plot a graph of ln(N) against time and calculate the modulus of the gradient
State the equation for half-life.
T1/2 = ln2 / decay constant
What is the activity of a sample?
The number of nuclei that decay per second
State the equation for activity.
A= N x decay constant
Why does activity follow the same exponential decay constant?
It is directly proportional to the number of nuclei
Why is activity normally used to calculate half-life rather than number of nuclei?
It is much easier to measure
How is half-life used in carbon dating?
Nuclei with a long half-life (eg C-14), is measured in a sample and compared to the initial amount (% is approx equal in all living things)
How is half-life used in medical diagnosis?
Short half-life nuclei is used in medicine as the half-life is short enough to limit exposure but long enough to carry out tests
How does half-life effect how a source is stored?
Long half-lives must be stored suitably to prevent nuclei from damaging the environment and the people around it
What force holds nuclei together?
The strong force
Why do protons experience repulsion?
Due to electromagnetic force between them
State 4 reasons why a nucleus will decay.
Too many neutrons
Too many protons
Too many nucleons
Too much energy
How does a nucleus with too many neutrons decay?
Beta minus emission, one of the neutrons turns into a proton and a beta minus particle and an antineutrino are released
What happens to the nucleon and proton number during beta minus emission?
Nucleon number stays constant
Proton number increases by 1
How does a nucleus with too many protons decay?
Beta plus emission - a proton changes into a neutron and a beta plus particle and a neutrino are released
Electron capture - an orbiting electron is combined with a proton and a neutron and a neutrino are formed
What happens to the nucleon and proton number during beta plus emission?
The nucleon number stays constant
Proton number increases by 1
How does a nucleus with too many nucleons decay?
Alpha emission
What happens to nucleon and proton number during alpha emission?
Nucleon number decreases by 4
Proton number decreases by 2
How does a nucleus with too much energy decay?
Gamma emission - usually occurs after a different type of decay
Why does gamma emission normally occur after another type of decay?
The nucleus becomes excited and has excess energy
Why does the number of protons and neutrons not increase uniformly for larger elements?
The electromagnetic repulsion becomes larger than the strong force, so more neutrons are needed to increase the distance between the protons and therefore decrease the EM force and keep the nucleus stable
How does the energy of the nucleus change during alpha emission?
It decreases
How is technetium-99m used in medical diagnosis?
Technetium is formed in an excited state, and will emit a gamma photon in order to reach ground state, which can be used for imaging
How can the nuclear radius of an atom be estimated?
Calculating the closest approach of a charged particle
Electron diffraction
How is closest approach to a nucleus calculated?
Eelec = 1/4piE0 x Q1Q2/r
Explain how electron diffraction is used to estimate nuclear radius.
The electrons are accelerated towards a thin film of material in front of a scree, causing them to diffract through gaps between nuclei
Plot a graph of intensity against diffraction angle and find the first min angle
Use the formula sinX = 0.61 x wavelength / R
What is the typical value of nuclear radius?
1 × 10-15m
How is nuclear radius dependent on nucleon number?
The higher the nucleon number, the wider the atomic radius
How can the relationship between nuclear radius and nucleon number be found from a graph of nuclear radius against nucleon number?
Log the relationship and plot a graph of ln(R) against ln(A)
The gradient gives the relationship and the y-intercept gives the value of ln(k) where k is a constant
State the equation linking nuclear radius and nucleon number.
R = R0A1/3
Use R=R0A1/3 to show that nuclear density is constant for all nuclei.
Density = mass/volume
A x m / 4/3piR³
A x m / 4/3pi(R03A)
m / 4/3piR03 = constant
State the calculated value of nuclear density.
1.45 × 1017 kgm-3
Why is the density of a nucleus much higher than the density of an atom?
Most of the atom is empty space
State the equation for nuclear energy.
E = mc2
What is mass defect?
The mass lost as energy when a nucleus is formed from its constituents
What is binding energy?
The energy required to separate the nucleus into its constituents (or released when it’s formed)
What is the atomic mass unit defined as?
1/12th of the mass of a carbon-12 atom
Convert 1u to kg.
x 1.661×10-27
A change of 1u means how much energy is released?
931.5MeV
How is mass defect calculated?
sum of nucleon masses - mass of nucleus
What is nuclear fission?
The splitting of a large nucleus into 2 smaller daughter nuclei
Why is energy released during nuclear fission?
The smaller daughter nuclei have a higher binding energy per nucleon than the larger nucleus
What is nuclear fusion?
When 2 smaller nuclei join to form one larger nucleus
Why is energy released during nuclear fusion?
The larger nucleus has a much higher binding energy per nucleon than the smaller nuclei
Which fission/fusion process releases more energy?
Fusion
Why can fusion only happen at high temperatures?
It takes large amounts of energy to overcome the electrostatic force of repulsion between the nuclei
What element has the highest binding energy per nucleon?
Iron
What process do elements smaller than iron undergo?
Fusion
What process do elements bigger than iron undergo?
Fission
How can the energy released in fusion/fission be calculated?
Calculate the energy difference between the nuclei
What process is used in nuclear power plants?
Fission
What safety risks are associated with nuclear power plants?
Meltdowns, radioactive products
How can nuclear fission be induced?
Thermal neutrons are fired into the uranium nucleus causing it to become unstable and decay
Why do faster moving neutrons rarely induce nuclear fission?
They collide with the nucleus and are bounced back rather than being absorbed
What are the products of nuclear fission?
2 daughter nuclei and at least one fission neutron
What happens to the fission neutron released from the uranium?
They go on to cause a chain reaction where each fission goes on to cause at least one more fission
What is meant by critical mass?
The minimum mass of fuel required to maintain a steady chain reaction of fissions
Give 3 key features of a nuclear reactor.
Moderator
Control rods
Coolant
Explain the purpose of a moderator in a nuclear reactor.
It slows down the neutrons released in fission reactions to thermal speeds
The fast-moving neutrons collide with moderator atoms and transfer some of their kinetic energy, slowing them down
The closer the size of the moderator atoms to the neutrons, the higher the proportion of momentum transferred, therefore the lower number of collision required to slow it to thermal speeds
What materials are used as moderators and why?
Graphite and water - inexpensive and not very reactive and close in size to neutrons
Explain the purpose of control rods in a nuclear reactor.
They absorb neutrons to control the chain reaction, controlling the amount of energy produced so it doesn’t become out of control
What materials are used as control rods and why?
Boron or cadmium as they can absorb neutrons without undergoing nuclear fission
Explain the purpose of a coolant in a nuclear reactor.
It absorbs the heat released during fission from the reactor, using it to make steam to power electricity-generating turbines
Why is water often used as a coolant in nuclear reactors?
It has a high specific heat capacity so can transfer large amounts of thermal energy