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What is the Kinetic Molecular Theory?
A molecular explanation of gases determined by 5 postulates and developed gas laws
What are the 5 postulates of the KMT?
1. Gases consist of tiny particeles which are so small, when compared, the volume of the gap between particles is negligble/zero.
2. There are no attractive (IMF) or repulsive froces between gas molecules.
3. Particles move in a constant random straight line motion unless they collide w molecules or the walls of a cointainer - these collisions cause pressure exerted by gas.
4. Molecules collide elastically or have no loss of KE.
5. KE is directly proportional to Kelvin Temperature of gas.
What are the characteristics of gases?
- Expand to fill any container
> random motion; no attractive forces
- Gases are fluid
> no attraction/replusion
- Gases have very low densities
> No vol = Lots of empty space
- Gases are compressible
> No vol = lots of empty space
- Gases undergo diffusion and effusion
> Random Motion
What are the properties of gases? Units?
Volume (V)
- Liters (L)
Pressure (P)
- Atmosphere (atm), kilopascal (kPa, mmHg, torr),
Temperature (T),
- Kelvin (K)
Number of molecules (n)
- Mole (n)
How do gases exert pressure?
By colliding with other particles or the wall - more collisions = more pressure
What are factors that affect gas pressure?
Amount of gas, volume, and temperature
How does the amount of gas affect gas pressure?
More Particles = More Pressure because more collisions
How does the volume of gas affect the pressure?
Less Volume = More pressure bc less volume means less space therefore more collisions
How does the temperature of the gas affect pressure?
Higher pressure = Higher KE = more collisions = higher pressure
What is the pressure conversion?
1atm=760 mmHg=760torr=101.3kPa
What is boyle's law?
P1V1 = P2V2 where temp is held constant - pressure and volume are inversely proportional
What is charles' law?
V1/T1 = V2/T2 where pressure is held constant -volume and temperature are directly proportional
What is Gay-Lussac's Law?
P1/T1 = P2/T2 where volume is held constant - pressure and temperature are directly proportional