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Rate Law for the Zero Order
Rate = k
Rate Law for the First Order
Rate = k[A]
Rate Law for the Second Order
Rate = k[A]^2
Integrated Rate Law for the Zero Order
[A] = -kt + [A]v0
Integrated Rate Law for the First Order
ln[A] = -kt + ln[A]v0
Integrated Rate law for the Second Order
1/[A] = kt + 1/[A]v0
Plot needed to give a straight line for the Zero Order
[A] versus t
Plot needed to give a straight line for the First Order
ln[A] versus t
Plot needed to give a straight line for the Second Order
1/[A] versus t
Relationship of rate constant to the slope of a straight line for the Zero Order
Slope = -k
Relationship of rate constant to the slope of a straight line for the First Order
Slope = -k
Relationship of rate constant to the slope of a straight line for the Second Order
Slope = k
Half-life for the Zero Order
tv1/2 = [A]v0/2k
Half-life for the First Order
tv1/2 = 0.693/k
Half-life for the Second Order
tv1/2 = 1/k[A]v0
Activation Energy symbol
Eva
Universal Gas Constant symbol
R
Kelvin Temperature symbol
T
Fraction of collisions with energy Eva or greater at temperature T symbols
e^-Eva/RT
Value of Eva formula
Slope = -Eva/R
The Arrhenius Equation
k = Ae^-Eva/RT
Frequency Factor symbol
A
![<p>[A] = -kt + [A]v0</p>](https://knowt-user-attachments.s3.amazonaws.com/aedfb904b40a4fb3934975b5ffb31f2c.jpeg)
![<p>ln[A] = -kt + ln[A]v0</p>](https://knowt-user-attachments.s3.amazonaws.com/eba60cb68c484000a8478d04b5341770.jpeg)
![<p>1/[A] = kt + 1/[A]v0</p>](https://knowt-user-attachments.s3.amazonaws.com/494aacaba2e040a2a999f9b252b8e7e6.jpeg)
![<p>tv1/2 = [A]v0/2k</p>](https://knowt-user-attachments.s3.amazonaws.com/fcf8d4c91a234cb9a3eaf0186a7a4872.jpeg)
![<p>tv1/2 = 1/k[A]v0</p>](https://knowt-user-attachments.s3.amazonaws.com/96bfc14438274fb78d09d9eaca35de78.jpeg)
Note
Flashcard