Chemistry- Kinetics

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Rate Law for the Zero Order

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22 Terms

1

Rate Law for the Zero Order

Rate = k

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2

Rate Law for the First Order

Rate = k[A]

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3

Rate Law for the Second Order

Rate = k[A]^2

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4

Integrated Rate Law for the Zero Order

[A] = -kt + [A]v0

<p>[A] = -kt + [A]v0</p>
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5

Integrated Rate Law for the First Order

ln[A] = -kt + ln[A]v0

<p>ln[A] = -kt + ln[A]v0</p>
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6

Integrated Rate law for the Second Order

1/[A] = kt + 1/[A]v0

<p>1/[A] = kt + 1/[A]v0</p>
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7

Plot needed to give a straight line for the Zero Order

[A] versus t

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8

Plot needed to give a straight line for the First Order

ln[A] versus t

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9

Plot needed to give a straight line for the Second Order

1/[A] versus t

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10

Relationship of rate constant to the slope of a straight line for the Zero Order

Slope = -k

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11

Relationship of rate constant to the slope of a straight line for the First Order

Slope = -k

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12

Relationship of rate constant to the slope of a straight line for the Second Order

Slope = k

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13

Half-life for the Zero Order

tv1/2 = [A]v0/2k

<p>tv1/2 = [A]v0/2k</p>
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14

Half-life for the First Order

tv1/2 = 0.693/k

<p>tv1/2 = 0.693/k</p>
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15

Half-life for the Second Order

tv1/2 = 1/k[A]v0

<p>tv1/2 = 1/k[A]v0</p>
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16

Activation Energy symbol

Eva

<p>Eva</p>
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17

Universal Gas Constant symbol

R

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18

Kelvin Temperature symbol

T

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19

Fraction of collisions with energy Eva or greater at temperature T symbols

e^-Eva/RT

<p>e^-Eva/RT</p>
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20

Value of Eva formula

Slope = -Eva/R

<p>Slope = -Eva/R</p>
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21

The Arrhenius Equation

k = Ae^-Eva/RT

<p>k = Ae^-Eva/RT</p>
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22

Frequency Factor symbol

A

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