Chemistry- Kinetics
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Last updated 2:23 PM on 9/22/22
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22 Terms
1
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Rate Law for the Zero Order
Rate = k
2
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Rate Law for the First Order
Rate = k[A]
3
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Rate Law for the Second Order
Rate = k[A]^2
4
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Integrated Rate Law for the Zero Order
[A] = -kt + [A]v0
![[A] = -kt + [A]v0](https://knowt-user-attachments.s3.amazonaws.com/aedfb904b40a4fb3934975b5ffb31f2c.jpeg)
5
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Integrated Rate Law for the First Order
ln[A] = -kt + ln[A]v0
![ln[A] = -kt + ln[A]v0](https://knowt-user-attachments.s3.amazonaws.com/eba60cb68c484000a8478d04b5341770.jpeg)
6
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Integrated Rate law for the Second Order
1/[A] = kt + 1/[A]v0
![1/[A] = kt + 1/[A]v0](https://knowt-user-attachments.s3.amazonaws.com/494aacaba2e040a2a999f9b252b8e7e6.jpeg)
7
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Plot needed to give a straight line for the Zero Order
[A] versus t
8
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Plot needed to give a straight line for the First Order
ln[A] versus t
9
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Plot needed to give a straight line for the Second Order
1/[A] versus t
10
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Relationship of rate constant to the slope of a straight line for the Zero Order
Slope = -k
11
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Relationship of rate constant to the slope of a straight line for the First Order
Slope = -k
12
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Relationship of rate constant to the slope of a straight line for the Second Order
Slope = k
13
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Half-life for the Zero Order
tv1/2 = [A]v0/2k
![tv1/2 = [A]v0/2k](https://knowt-user-attachments.s3.amazonaws.com/fcf8d4c91a234cb9a3eaf0186a7a4872.jpeg)
14
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Half-life for the First Order
tv1/2 = 0.693/k
15
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Half-life for the Second Order
tv1/2 = 1/k[A]v0
![tv1/2 = 1/k[A]v0](https://knowt-user-attachments.s3.amazonaws.com/96bfc14438274fb78d09d9eaca35de78.jpeg)
16
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Activation Energy symbol
Eva
17
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Universal Gas Constant symbol
R
18
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Kelvin Temperature symbol
T
19
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Fraction of collisions with energy Eva or greater at temperature T symbols
e^-Eva/RT
20
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Value of Eva formula
Slope = -Eva/R
21
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The Arrhenius Equation
k = Ae^-Eva/RT
22
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Frequency Factor symbol
A
