Chemistry- Kinetics

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22 Terms

1
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Rate Law for the Zero Order
Rate = k
2
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Rate Law for the First Order
Rate = k[A]
3
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Rate Law for the Second Order
Rate = k[A]^2
4
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Integrated Rate Law for the Zero Order
[A] = -kt + [A]v0
[A] = -kt + [A]v0
5
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Integrated Rate Law for the First Order
ln[A] = -kt + ln[A]v0
ln[A] = -kt + ln[A]v0
6
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Integrated Rate law for the Second Order
1/[A] = kt + 1/[A]v0
1/[A] = kt + 1/[A]v0
7
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Plot needed to give a straight line for the Zero Order
[A] versus t
8
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Plot needed to give a straight line for the First Order
ln[A] versus t
9
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Plot needed to give a straight line for the Second Order
1/[A] versus t
10
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Relationship of rate constant to the slope of a straight line for the Zero Order
Slope = -k
11
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Relationship of rate constant to the slope of a straight line for the First Order
Slope = -k
12
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Relationship of rate constant to the slope of a straight line for the Second Order
Slope = k
13
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Half-life for the Zero Order
tv1/2 = [A]v0/2k
tv1/2 = [A]v0/2k
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Half-life for the First Order
tv1/2 = 0.693/k
tv1/2 = 0.693/k
15
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Half-life for the Second Order
tv1/2 = 1/k[A]v0
tv1/2 = 1/k[A]v0
16
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Activation Energy symbol
Eva
Eva
17
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Universal Gas Constant symbol
R
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Kelvin Temperature symbol
T
19
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Fraction of collisions with energy Eva or greater at temperature T symbols
e^-Eva/RT
e^-Eva/RT
20
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Value of Eva formula
Slope = -Eva/R
Slope = -Eva/R
21
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The Arrhenius Equation
k = Ae^-Eva/RT
k = Ae^-Eva/RT
22
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Frequency Factor symbol
A