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Equilibrium crystallisation
crystals remain in contact with melt and re-equilibrate
Fractional crystallisation
crystals are removed causing melt to evolve
Why fractional crystallisation matters
produces strong enrichment of incompatible elements
Rayleigh equation
Cl = C0F^(D−1) describes melt evolution
Bulk distribution coefficient
weighted average D accounting for all minerals
Partial melting behaviour
low melt fractions enrich incompatible elements
REE patterns in melting
steep slopes indicate low degree melting
Eu anomaly meaning
indicates plagioclase control or redox effects
Fun exam fact
trace element modelling can identify which minerals crystallised first
Diagram card – Crystallisation
draw REE patterns for fractional crystallisation
Calculation card – Rayleigh
show how decreasing F increases Cl for D ≪ 1