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Lecture 13: Physical Properties
soil taxonomy
a soil classification system consisting of six hierarchical categories based on observable soil characteristics. The system recognizes 12 soil orders.
hue
intensity of yellow/red (pages)
value
brightness (up/down)
chroma
saturation (side to side)
hydrometer
An instrument for determining the density of solids and liquids by flotation.
stoke's law
An equation relating to the terminal settling velocity of a smooth, rigid sphere in a viscous fluid of known density and viscosity to the diameter of the sphere when subjected to a known force field. It is used in the particle size analysis of soils by the hydrometer method
macroaggregates
Soil particles joined together to form larger discrete particles of various shapes and sizes, visible to the naked eye. (0.25-5 mm)
microaggregates
Intimate association of soil particles, often clay-humus, not visible to the naked eye. (0.002-0.25 mm)
Flocculation
the process by which colloidal (i.e. clay-size) particles join together
Shrink and Swell
soil swells with moisture and shrinks when dry
soil density
weight of a unit volume of soil expressed on either a wet basis (including soil and water) or on a dry basis (soil only, most common)
bulk density
The mass of dry soil per unit volume, including the air space, and organic matter
particle density
the mass per unit volume of the soil particles, only including solids
most common mineral particle density
2.65 g/cm3
porosity
The percentage of the total volume of a rock or sediment that consists of open spaces.
Lecture 14: Soil Water
capillary flow
Water moves up hill (or in any direction) due to the forces of adhesion and cohesion - movement under tension or negative pressure
soil water potential
measures the energy status of water
-more negative: water is held tight
-less negative: water isn't held tight
water tends to move from high potential (less negative) to low potential (more negative)
gravitational potential
Potential energy that depends on the height of an object
matric potential
the potential energy generated by the attractive forces between water molecules and soil particles
hydrostatic potential
Energy due to the weight of the water at a given elevation and pressure
osmotic potential
The tendency of water to move across a semi-permeable membrane into a solution
tensiometers
instrument used to measure soil moisture
Bulk Density equation
dry mass/volume
Particle Density equation
dry mass (g) of soil / volume of soil particles
saturation
all pore spaces filled with water (max retentive capacity)
field capacity
after gravitational water drains
wilting point
water held tightly by micropores, no longer available for plants
hygroscopic coefficient
remaining water no longer considered liquid phase
Lecture 15: Cation Exchange Capacity
soil colloids
smallest fraction of soil particles, composed of clays and humus
Cation Exchange Capacity (CEC)
the ability of a particular soil to absorb and release cations
tetrahedron (SiO4)
silicon shares half the charge from its 4 oxygens
octahedron [Al(OH)6, Fe(OH)6]
aluminum/iron share half the charge from its 6 hydroxyls
Tetrahedral sheets
composed of 4 oxygen atoms in a tetrahedron with a silicon atom in the center
-si tetrahedra share basal oxygen
-apical oxygens shared with octahedral sheets
Isomorphous substitution
the replacement of one atom by another of similar size in a crystal lattice without disrupting or changing the crystal structure of the mineral
low pH= -log [H+]
low pH-> a lot of protons (hydrogen)
humus
large irregular organic molecules; varied composition
Lecture 16: Soil pH
alkalinity
capability to resist acidification (buffering)
Cation weathering
Ca-silicate + 2H -> H4SiO4 + Ca
Carbonate inputs
CO3 + H -> HCO3 + H -> H2CO3
Soil pH influences
acidifying:
-precipitation, and leaching
-plant and microbial activity
-accumulation of OM
alkalizing:
-cation weathering
-carbonate inputs
exchange of H+ to help maintain pH
CO2 + H2O ↔ H2CO3 ↔ HCO3- + H+
weathered Al causes hydrolysis
Al + 3H2O -> Al(OH)3 + 3H
nitrification
NH4 + 2O2 -> H2O + 2H + NO3
sulfur oxidation
2FeS2 + 7O2 + 2H2O -> 2FeSO4 + 4H + 2SO4
Additions of Elemental Sulfur (Treating Basic)
2H2O +3O2 + 2S -> 2SO4 + 4H
Lime Added to soil (Treating Acidic)
CaMg (CO3)2 + H2O -> Ca + Mg + 2HCO3
HCO3 + H -> H20 + CO2
NH4 additions (Treating Basic)
2O2 + NH4 -> NO3 + H2O + 2H
Lecture 17: Soil Biology, Organic Matter, and Best Management Practices
Living Biomass
bacteria, fungi, fine plant roots
What is soil organic matter?
all carbon compounds in soil that are/were components of a living organism
identifiable dead tissue
detritus
humic substances
irregular complex polymers, resistant to breakdown
nonhumic substances
identifiable byproducts of soil microbial activity
soil biota
organisms that spend all or a portion of their lifecycle within the soil or on its immediate surface
bacteria and fungi
most abundant organisms within soil, 80-90% of soil metabolic activity
herbivores
feed on living plants
detritivores
feed on dead plant tissue
predators
feed on smaller organisms
Actinomycetes
need aerobic conditions, decompose complex organics, furthering humus development, sensitive to low pH and high water content, produce over 2/3rds of all antibiotics
Saprophytic fungi
effective at degrading large organic compounds using extracellular enzymes, litter decomposers, brown-rot, white-rot fungi, abundant in upland soils, more resistant to desiccation and low pH than bacteria
litter decomposers
ephemeral substrates
brown-rot fungi
cellulose, not lignin
white-rot fungi
lignin and cellulose
Mycorrhizae
act as an extension of plant root system, contribute soil nutrients (especially phosphorus), and add water to plant in exchange for carbon, 90% of all plant species have some relation (except agriculture)
ex: ectomycorrhiza, arboscular mycorrhiza
Microfauna
Small, often microscopic animals, especially those that live in the soil.
Nematodes
predatory roundworms, 4-100 micrometers in diameter, activity releases more plant available nutrients via predation on bacteria
Protozoa
one-cell organisms that feeds on soil bacteria and have free movement via cilia or flagella
Earthworms
create burrows that leave behind casts, OM mixed and shredded as it passes through gut
-no native earthworms in northern US
Epigeic, Endogeic, Anecic
Earthworm sizes in order
Rise in CN =
decrease in Nitrogen, and increase in Carbon
Lowering of CN =
increase of CN
Libile
Changing rapidly and often (repeating compounds like Hemicellulose, cellulose, chitin, and starch)
recalcitrant
hard to break down, ex: lignin
humus made up of =
lignin